1,2-Benzenedicarbonitrile, 4-[(2-methyl-8-quinolinyl)oxy]-

Base Information

Chemical Name:1,2-Benzenedicarbonitrile, 4-[(2-methyl-8-quinolinyl)oxy]-
CAS No.:876904-46-0
Molecular Formula:C18H11N3O
Molecular Weight:285.305
Hs Code.:

Synonyms:

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Chemical Property of 1,2-Benzenedicarbonitrile, 4-[(2-methyl-8-quinolinyl)oxy]-

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Technology Process of 1,2-Benzenedicarbonitrile, 4-[(2-methyl-8-quinolinyl)oxy]-

There total 1 articles about 1,2-Benzenedicarbonitrile, 4-[(2-methyl-8-quinolinyl)oxy]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.8%

: 826-81-3
2-methyl-8-quinolinol

: 31643-49-9
4-Nitrophthalonitrile

: 876904-46-0
4-(2-methyl-8-oxy-quinoline) phthalonitrile

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 45 ℃; for 2h; Inert atmosphere;
DOI:10.1016/j.molstruc.2012.04.046

Reference yield: 36.7%

: 876904-46-0
4-(2-methyl-8-oxy-quinoline) phthalonitrile

: 85218-66-2
4-(4-hydroxycarbonylphenoxy)phthalonitrile

: 9,16,23-tri(4-carboxy-phenoxy)-2-(2-methyl-8-oxy-quinoline) zinc phthalocyanine

Guidance literature:: With zinc diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In pentan-1-ol; at 160 ℃; for 20h; Inert atmosphere;
DOI:10.1016/j.molstruc.2012.04.046

Reference yield: 36.7%

: 876904-46-0
4-(2-methyl-8-oxy-quinoline) phthalonitrile

: 557-34-6
zinc diacetate

: 85218-66-2
4-(4-hydroxycarbonylphenoxy)phthalonitrile

: 9,16,23-tri(4-carboxy-phenoxy)-2-(2-methyl-8-oxy-quinoline) zinc phthalocyanine

Guidance literature:: With catalyst: 1,8-diazabicyclo [5.4.0]-undec-7-ene DBU; In pentan-1-ol; under N2; 4-(2-methyl-8-oxy-quinoline) phthalonitrile (0.5 mmol), 4-(4-carboxy-phenoxy) phthalonitrile (1.5 mmol), Zn(CH3CO2)2 (0.5 mmol) and a catalytic amt. of DBU in dry 1-pentanol was heated at 160°C with stirring for 20 h; cooling; addn. of methanol for pptn.; the solid was sepd. by filtration, washed with methanol and ethanol and dried in vac.; silica gel column chromy. (elution with DMF:CH3OH = 1:1 (v/v)); the solvent was removed under reduced pressure; elem. anal.;
DOI:10.1016/j.molstruc.2012.04.046