Dichlorobis(pyridine)palladium(II)

Base Information

• Chemical Name: Dichlorobis(pyridine)palladium(II)
• CAS No.: 14872-20-9
• Molecular Formula: C₁₀H₁₀Cl₂N₂Pd
• Molecular Weight: 335.529
• European Community (EC) Number: 677-795-1
• Mol file: 14872-20-9.mol

Synonyms:Dichlorobis(pyridine)palladium(II);14872-20-9;dichloropalladium;pyridine;Palladium, dichlorobis(pyridine)-;Bis(pyridine)palladium dichloride;SCHEMBL2009507;MFCD00792248;?DICHLOROBIS(PYRIDINE)PALLADIUM(II);FT-0637153;F75021

Chemical Property of Dichlorobis(pyridine)palladium(II)

Chemical Property:

• Vapor Pressure: 22.8mmHg at 25°C
• Boiling Point: 106.4°Cat760mmHg
• Flash Point: 4.4°C
• PSA: 25.78000
• Density: g/cm³
• LogP: 3.54220
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 333.92558
• Heavy Atom Count: 15
• Complexity: 33.7

Purity/Quality:

98% ^*data from raw suppliers

BIS(PYRIDINE)PALLADIUM(II) CHLORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 20/21/22
• Safety Statements: 22-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=NC=C1.C1=CC=NC=C1.Cl[Pd]Cl

Technology Process of Dichlorobis(pyridine)palladium(II)

There total 22 articles about Dichlorobis(pyridine)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

pyridinium tetrachloropalladate (II) → trans dichlorobispyridine palladium (II) (14872-20-9,15227-47-1,14052-12-1)

Guidance literature:

In neat (no solvent); byproducts: HCl; isothermal decompn. at 140°C; elem. anal.;

Reference yield: 93.0%

pyridine (110-86-1) + palladium dichloride → dichlorobis(pyridine)palladium(II) (14872-20-9,15227-47-1,14052-12-1)

Guidance literature:

In methanol; at 20 ℃; for 3h;

DOI:10.1039/d0cc02262d

Reference yield: 90.0%

N-benzyl-2-methylimidazole (13750-62-4) + chloroacetone (78-95-5) → trans dichlorobispyridine palladium (II) (14872-20-9,15227-47-1,14052-12-1) + C14H17N2O(1+)*Cl(1-)

Guidance literature:

In tetrahydrofuran; for 48h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1021/om500834y

upstream raw materials:

bis(μ-chloro)bis[1-3-η3-(1-chloromethyl)-1-buten-3-yl]dipalladium(II)

pyridine

PdCl₂(P(C₆H₅)(2-C₆H₄Cl)2)2

pyridine-2-carbaldehyde

Downstream raw materials:

PdCl₂(PPh₃)(py)

tetramminepalladium(II) chloride