Vinyl Chloride

Base Information

• Chemical Name: Vinyl Chloride
• CAS No.: 75-01-4
• Deprecated CAS: 1187028-37-0
• Molecular Formula: C2H3Cl
• Molecular Weight: 62.4988
• Hs Code.: 2903210000
• European Community (EC) Number: 200-831-0
• ICSC Number: 0082
• UN Number: 1086
• UNII: WD06X94M2D
• DSSTox Substance ID: DTXSID8021434
• Nikkaji Number: J2.387F
• Wikipedia: Vinyl chloride,Bakelite,Vinyl_chloride
• Wikidata: Q338869
• NCI Thesaurus Code: C936
• Metabolomics Workbench ID: 51742
• ChEMBL ID: CHEMBL2311071
• Mol file: 75-01-4.mol

Synonyms:Chloride, Vinyl;Chloroethylene;Vinyl Chloride

Chemical Property of Vinyl Chloride

Chemical Property:

• Appearance/Colour: colourless gas
• Melting Point: -153.8 °C(lit.)
• Refractive Index: n20/D 1.3700(lit.)
• Boiling Point: -13.4 °C(lit.)
• Flash Point: -78 °F
• PSA: 0.00000
• Density: 0.918 g/cm³
• LogP: 1.36870
• XLogP3: 1.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 61.9923278
• Heavy Atom Count: 3
• Complexity: 10.3
• Transport DOT Label: Flammable Gas

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s): F+; T
• Hazard Codes: F+; T

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Plastics & Rubber -> Vinyl Halides
• Canonical SMILES: C=CCl
• Recent ClinicalTrials: Vitamin C Infusion for the Treatment of Severe 2019-nCoV Infected Pneumonia
• Inhalation Risk: A harmful concentration of this gas in the air will be reached very quickly on loss of containment.
• Effects of Short Term Exposure: The liquid may cause frostbite. The substance is irritating to the eyes. The substance may cause effects on the central nervous system. This may result in lowering of consciousness, convulsions and seizures. Medical observation is indicated.
• Effects of Long Term Exposure: The substance may have effects on the liver, spleen, blood, peripheral blood vessels and tissue and bones of the fingers. Animal tests show that this substance possibly causes toxicity to human reproduction or development. This substance is carcinogenic to humans.

Technology Process of Vinyl Chloride

There total 187 articles about Vinyl Chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-<2-<(2-chloroethyl)sulfinyl>-1,1-dimethylethyl>3-cyclohexyl-1-nitrosourea → thioformaldehyde (865-36-1,30699-99-1) + chloroethylene (75-01-4,9002-86-2) + Cyclohexyl isocyanate (3173-53-3) + 1,3-Dicyclohexylurea (2387-23-7) + acetone (67-64-1)

Guidance literature:

In water; Product distribution; other sulfoxide-substituted nitrosoureas under aqueous decomposition conditions;

DOI:10.1021/ja00339a029

Reference yield:

1-Bromo-2-chloroethane (107-04-0) → chloroethylene (75-01-4,9002-86-2) + hydrogen bromide (10035-10-6,12258-64-9)

Guidance literature:

Reference yield:

1,1,1-trichloroethane (71-55-6,74552-83-3) → dimethylacetylene (503-17-3) + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + 2,3-dimethylbutene (590-19-2) + chloroethylene (75-01-4,9002-86-2) + chloroacetylene (593-63-5) + acetaldehyde (75-07-0,9002-91-9) + acetic acid (64-19-7,77671-22-8) + prop-1-yne (74-99-7)

Guidance literature:

With vanadium sulfate; water; at 20 ℃; for 0.333333h;

DOI:10.1002/chem.201202918

upstream raw materials:

1,1-dichloroethane

ethene

cis-dichloro(2-chlorovinyl) arsine

1-methyl-4-nitrosobenzene

Downstream raw materials:

methoxyethene

ethenyltrimethylsilane

sulfure de methyle et de 2-chloroethyle

1,1,3-trichloro-butane

Refernces

• 1、 Hu, Yubing,Wang, Yan,Wang, Yulian,Li, Wei,Zhang, Jinli,Han, You. "High performance of supported Cu-based catalysts modulated via phosphamide coordination in acetylene hydrochlorination". . . Retrieved 2020.
• 2、 Hu, Di,Wang, Lu,Wang, Feng,Wang, Jide. "Active carbon supported S-promoted Bi catalysts for acetylene hydrochlorination reaction". . p. 1413 - 1416. Retrieved 2018.
• 3、 Xin-Huang,Yu, Feng,Zhu, Ming-Yuan,Ouyang, Fei-Hong,Dai, Bin,Dan, Jian-Ming. "Hydrochlorination of acetylene using expanded multilayered vermiculite (EML-VMT)-supported catalysts". . p. 1101 - 1104. Retrieved 2015.
• 4、 Zhao, Jigang,Zeng, Junjian,Cheng, Xiaoguang,Wang, Lei,Yang, Henghua,Shen, Benxian. "An Au-Cu bimetal catalyst for acetylene hydrochlorination with renewable γ-Al2O3 as the support". . p. 16727 - 16734. Retrieved 2015.
• 5、 Li, Xiaoyan,Nian, Yao,Shang, Shanshan,Zhang, Haiyang,Zhang, Jinli,Han, You,Li, Wei. "Novel nonmetal catalyst of supported tetraphenylphosphonium bromide for acetylene hydrochlorination". . p. 188 - 198. Retrieved 2019.
• 6、 Ma, Pelhua,Liu, Julin,Chen, Guancheng,Chu, Minxiong,Jing, Yan,Wu, Bin. "Continuous-wave CO2 Lase-induced Chain Reaction of 1,2-Dichloroethane". . p. 4171 - 4176. Retrieved 1993.
• 7、 Aramini, Matteo,Freakley, Simon J.,Gianolio, Diego,Gibson, Emma K.,Hutchings, Graham J.,Johnston, Peter,Kondrat, Simon A.,Malta, Grazia,Morgan, David J.,Thompson, Paul B. J.,Wells, Peter P.. "In situ K-edge X-ray absorption spectroscopy of the ligand environment of single-site Au/C catalysts during acetylene hydrochlorination". . p. 7040 - 7052. Retrieved 2020.
• 8、 Lan, Guojun,Wang, Yan,Qiu, Yiyang,Wang, Xiaolong,Liang, Ji,Han, Wenfeng,Tang, Haodong,Liu, Huazhang,Liu, Jian,Li, Ying. "Wheat flour-derived N-doped mesoporous carbon extrudate as superior metal-free catalysts for acetylene hydrochlorination". . p. 623 - 626. Retrieved 2018.
• 9、 Zhao, Wei,Sun, Mengxia,Zhang, Haiyang,Dong, Yanzhao,Li, Xiaoyan,Li, Wei,Zhang, Jinli. "Catalytic dehydrochlorination of 1,2-dichloroethane to produce vinyl chloride over N-doped coconut activated carbon". . p. 104071 - 104078. Retrieved 2015.
• 10、 Dix, Edward J.,Herman, Michael S.,Goodman, Joshua L.. "The 1,2-hydrogen rearrangement of methylchlorocarbene: Contribution of quantum mechanical tunneling". . p. 10424 - 10425. Retrieved 1993.