1-(Bromomethyl)-3-chloro-2-methylbenzene

Base Information

Chemical Name:1-(Bromomethyl)-3-chloro-2-methylbenzene
CAS No.:90369-76-9
Molecular Formula:C8H8BrCl
Molecular Weight:219.509
Hs Code.:
DSSTox Substance ID:DTXSID601274371
Nikkaji Number:J1.215.504B
Mol file:90369-76-9.mol

Synonyms:1-(Bromomethyl)-3-chloro-2-methylbenzene;90369-76-9;3-CHLORO-2-METHYLBENZYL BROMIDE;SCHEMBL724659;3-chloro-2-methylbenzylbromide;ORGIHYDPMFXTEZ-UHFFFAOYSA-N;DTXSID601274371;MFCD12025000;AS-36891;1-Chloro-2-methyl-3-(bromomethyl)benzene;FT-0715213;Benzene, 1-(bromomethyl)-3-chloro-2-methyl-;EN300-2967225

Suppliers and Price of 1-(Bromomethyl)-3-chloro-2-methylbenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Ambeed
1-(Bromomethyl)-3-chloro-2-methylbenzene 95%
5g
$ 252.00

Ambeed
1-(Bromomethyl)-3-chloro-2-methylbenzene 95%
1g
$ 92.00

Ambeed
1-(Bromomethyl)-3-chloro-2-methylbenzene 95%
250mg
$ 46.00

Ambeed
1-(Bromomethyl)-3-chloro-2-methylbenzene 95%
100mg
$ 31.00

Alichem
3-Chloro-2-methylbenzylbromide
1g
$ 1564.50

Alichem
3-Chloro-2-methylbenzylbromide
500mg
$ 839.45

Alichem
3-Chloro-2-methylbenzylbromide
250mg
$ 484.80

Total 6 raw suppliers

Chemical Property of 1-(Bromomethyl)-3-chloro-2-methylbenzene

Chemical Property:

PSA：0.00000
LogP:3.54330
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:217.94979
Heavy Atom Count:10
Complexity:105

Purity/Quality:

99% ^*data from raw suppliers

1-(Bromomethyl)-3-chloro-2-methylbenzene 95% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=C(C=CC=C1Cl)CBr

Technology Process of 1-(Bromomethyl)-3-chloro-2-methylbenzene

There total 5 articles about 1-(Bromomethyl)-3-chloro-2-methylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 90369-75-8
(3-chloro-2-methyl-phenyl)methanol

: 90369-76-9
1-(bromomethyl)-3-chloro-2-methyl benzene

Guidance literature:: With pyridine; phosphorus tribromide; In benzene; for 2h;
DOI:10.1021/jo00188a004

Reference yield:

: 7499-08-3
3-chloro-2-methylbenzoic acid

: 90369-76-9
1-(bromomethyl)-3-chloro-2-methyl benzene

Guidance literature:: Multi-step reaction with 2 steps

1: lithium aluminium tetrahydride / tetrahydrofuran / 6.5 h / -78 - 20 °C / Inert atmosphere

2: triphenylphosphine; carbon tetrabromide / diethyl ether / 1.33 h / 20 °C / Inert atmosphere

With lithium aluminium tetrahydride; carbon tetrabromide; triphenylphosphine; In tetrahydrofuran; diethyl ether;

Reference yield:

: 118-69-4
2,6-dichlorotoluene

: 90369-76-9
1-(bromomethyl)-3-chloro-2-methyl benzene

Guidance literature:: Multi-step reaction with 2 steps

1: 1) Mg, 1,2-Dibromoethane / 1) in THF under refluxtemp., 2) under cooling, 45 min -> 12 h, refluxtemp.

2: 94 percent / PBr₃, Py_. / benzene / 2 h

With pyridine; phosphorus tribromide; magnesium; ethylene dibromide; In benzene;
DOI:10.1021/jo00188a004