Fluoranthene

Base Information

• Chemical Name: Fluoranthene
• CAS No.: 206-44-0
• Molecular Formula: C16H10
• Molecular Weight: 202.255
• Hs Code.: 2902.90 Oral rat LD50: 2 gm/kg
• European Community (EC) Number: 205-912-4
• NSC Number: 6803
• UN Number: 1325,3082
• UNII: 360UOL779Z
• DSSTox Substance ID: DTXSID3024104
• Nikkaji Number: J2.973D
• Wikipedia: Fluoranthene
• Wikidata: Q423462
• Metabolomics Workbench ID: 54809
• ChEMBL ID: CHEMBL355014
• Mol file: 206-44-0.mol

Synonyms:fluoranthene

Chemical Property of Fluoranthene

Chemical Property:

• Appearance/Colour: Light yellow fine crystals
• Vapor Pressure: 1.73E-05mmHg at 25°C
• Melting Point: 109 °C
• Refractive Index: 1.851
• Boiling Point: 374.998 °C at 760 mmHg
• Flash Point: 168.375 °C
• PSA: 0.00000
• Density: 1.249 g/cm³
• LogP: 4.48720
• Storage Temp.: APPROX 4°C
• Water Solubility.: insoluble
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 202.078250319
• Heavy Atom Count: 16
• Complexity: 243
• Transport DOT Label: Flammable Solid

Purity/Quality:

99% ^*data from raw suppliers

Fluoranthene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn, N, F, T
• Hazard Codes: Xn,N,F,T
• Statements: 22-36/37/38-40-67-65-50/53-38-11-39/23/24/25-23/24/25-52/53-50
• Safety Statements: 37/39-26-36/37-24/25-23-62-61-60-45-16-7

MSDS Files:

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Polycyclic Aromatic Hydrocarbons
• Canonical SMILES: C1=CC=C2C(=C1)C3=CC=CC4=C3C2=CC=C4
• Uses: Fluoranthene is a component of polynuclear aromatic hydrocarbons, also known as polycyclic aromatic hydrocarbons, and is usually bound to small particulate matter present in urban air, industrial and natural combustion emissions, and cigarette smoke. Fluoranthene can be used as a starting material in the synthesis of:Polyfluoranthene (PFA) based conducting polymer (PFA) by electrochemical anodic oxidation using Lewis acid catalyst.Substituted fluorenones.Fluorescence-emitting oligofluoranthene (OFA) nanorods by oxidative oligomerization.

Technology Process of Fluoranthene

There total 183 articles about Fluoranthene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

4-phenylnaphtho[2,3-c]furan-1,3-dione (1985-37-1) → 1-phenylnaphthalene (605-02-7) + fluoranthene (206-44-0) + acephenanthrylene (201-06-9) + aceanthrylene (202-03-9)

Guidance literature:

Yields of byproduct given; 1.) 960 deg C, 0.02 mm, 2.) 180-200 deg C, 1.25 h;

Reference yield: 24.0%

2-(naphthalen-1-yl)phenylamine (92855-12-4) + phenylacetylene (536-74-3) → 1-phenylnaphthalene (605-02-7) + fluoranthene (206-44-0) + 6-phenylbenzo[c]phenanthrene (64954-44-5)

Guidance literature:

With fac-tris(2-phenylpyridinato-N,C₂')iridium(III); tert.-butylnitrite; In acetonitrile; at 20 ℃; for 15h; Sealed tube; Irradiation;

DOI:10.1021/acs.joc.7b00413

Reference yield:

small intercontinental ballistic missile propellant → pyrene (129-00-0) + benzo[e]acephenanthrylene (205-99-2) + fluoranthene (206-44-0) + chrysene (218-01-9)

Guidance literature:

With oxygen; at 1023.85 - 1161.85 ℃; Further byproducts given. Title compound not separated from byproducts; Formation of xenobiotics;

DOI:10.1016/S0045-6535(00)00228-9

upstream raw materials:

1-cyclohex-1-enyl-naphthalene

1-phenylnaphthalene

1,2,3,10b-tetrahydrofluoranthene

acetylene

Downstream raw materials:

4-fluoranthen-3-yl-4-oxo-butyric acid

4-(8-fluoranthenyl)-4-oxobutyric acid

6--6-oxo-capronsaeure

3-hydroxyfluoranthene

Refernces

• 1、 Rehner. "". . p. 2243. Retrieved 1940.
• 2、 Maly, Ernest. "A Microsynthesis of Fluoranthene". . p. 1103 - 1104. Retrieved 1981.
• 3、 Gonzalez, Juan J.,Francesch, Andres,Cardenas, Diego J.,Echavarren, Antonio M.. "Steric Hindrance Facilitated Synthesis of Enynes and Their Intramolecular [4 + 2] Cycloaddition with Alkynes". . p. 2854 - 2857. Retrieved 1998.
• 4、 Preda, Dorin V.,Scott, Lawrence T.. "Phenyl migrations in dehydroaromatic compounds. A new mechanistic link between alternant and nonalternant hydrocarbons at high temperatures". . p. 1489 - 1492. Retrieved 2000.
• 5、 Bobkova,Stokolos,Garifullin. "Mechanisms of Heptane Degradation and Product Formation in Microwave Discharge". . p. 336 - 340. Retrieved 2019/08/15.
• 6、 Yan, Jianming,Rahman, Md. Shafiqur,Yoshikai, Naohiko. "Pd-Catalyzed Annulation of 1-Halo-8-arylnaphthalenes and Alkynes Leading to Heptagon-Embedded Aromatic Systems". . p. 9395 - 9399. Retrieved 2019/01/04.