1-Phenylnaphthalene

Base Information

• Chemical Name: 1-Phenylnaphthalene
• CAS No.: 605-02-7
• Molecular Formula: C16H12
• Molecular Weight: 204.271
• European Community (EC) Number: 210-081-6
• NSC Number: 5257
• UNII: 10NXC4G45Q
• DSSTox Substance ID: DTXSID8060539
• Nikkaji Number: J134.382C
• Wikidata: Q27251151
• Mol file: 605-02-7.mol

Synonyms:1-PHENYLNAPHTHALENE;605-02-7;Naphthalene, 1-phenyl-;1-Phenyl-naphthalene;C16H12;UNII-10NXC4G45Q;10NXC4G45Q;NSC 5257;NSC-5257;EINECS 210-081-6;PHENYLNAPHTHALENE;phenyl-napthalene;1-phenylnaphtalene;1-phenylnapthalene;p-(4-naphthyl)benzene;1-Phenylnaphthalene, 96%;DTXSID8060539;NSC5257;MFCD00003983;AKOS004901779;AC-18700;AS-57186;CS-0187929;FT-0608262;P0632;D82132;1-Phenylnaphthalene 10 microg/mL in Acetonitrile;A832755;10-Deacetylbaccatin III pound 10-DAB III pound(c);Q27251151

Chemical Property of 1-Phenylnaphthalene

Chemical Property:

• Appearance/Colour: clear colorless to yellow viscous liquid
• Vapor Pressure: 0.000219mmHg at 25°C
• Refractive Index: n20/D 1.664(lit.)
• Boiling Point: 336.4 °C at 760 mmHg
• Flash Point: 148.2 °C
• PSA: 0.00000
• Density: 1.081 g/cm³
• LogP: 4.50680
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 204.093900383
• Heavy Atom Count: 16
• Complexity: 214

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Safety Statements: S24/25:Avoid contact with skin and eyes.

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Aromatic Hydrocarbons
• Canonical SMILES: C1=CC=C(C=C1)C2=CC=CC3=CC=CC=C32

Technology Process of 1-Phenylnaphthalene

There total 463 articles about 1-Phenylnaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

1-phenyl-3,4-dihydronaphthalene (7469-40-1) → 1-phenylnaphthalene (605-02-7) + 1-phenyl-1,2,3,4-tetrahydronaphthalene (3018-20-0) + 1-phenyl-1,4-dihydronaphthalene (13387-49-0)

Guidance literature:

With propylamine; Irradiation;

Reference yield: 32.4%

1-bromovinylbenzene (98-81-7) → styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 2,5-Diphenyl-thiophene (1445-78-9) + 1-phenylnaphthalene (605-02-7) + α-styryl-β-styryl sulfide + phenylacetylene (536-74-3) + Benzo[b]thiophene (95-15-8,11095-43-5)

Guidance literature:

With hydrogen sulfide; at 150 ℃; for 7.5h; Product distribution; Heating; other time, other temperatures,;

Reference yield: 20.0%

1-bromovinylbenzene (98-81-7) → styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 2,5-Diphenyl-thiophene (1445-78-9) + 1-phenylnaphthalene (605-02-7) + α-styryl-β-styryl sulfide

Guidance literature:

With hydrogen sulfide; at 170 ℃; for 4h;

upstream raw materials:

pyrrolidine

diethyl ether

phenyllithium

1-Chloronaphthalene

Downstream raw materials:

2-phenylnaphthalene

fluoranthene

1-nitro-4-phenyl-naphthalene

1-bromo-4-phenylnaphthalene

Refernces

• 1、 Hone, Neal D.,Davies, Stephen G.,Devereux, Nicholas J.,Taylor, Sara L.,Baxter, Anthony D.. "A highly acid labile silicon linker for solid phase synthesis". . p. 897 - 900. Retrieved 1998.
• 2、 Galletero, Mariì?a S.,Corma, Avelino,Ferrer, Beleì?n,Forneì?s, Vicente,Garciì?a, Hermenegildo. "Confinement effects at the external surface of delaminated zeolites (ITQ-2): An inorganic mimic of cyclodextrins". . p. 1135 - 1141. Retrieved 2003.
• 3、 Wang, Jin-Xian,Yang, Yihua,Wei, Bangguo. "Pd(II)-catalyzed synthesis of unsymmetrical biaryls from tetraphenylborate and aryl halides under microwave activation". . p. 2063 - 2069. Retrieved 2004.
• 4、 Artok, Levent,Bulut, Hatice. "Heterogeneous Suzuki reactions catalyzed by Pd(0)-Y zeolite". . p. 3881 - 3884. Retrieved 2004.
• 5、 Park, Tae-Hong,Hickman, Amanda J.,Koh, Kyoungmoo,Martin, Stephen,Wong-Foy, Antek G.,Sanford, Melanie S.,Matzger, Adam J.. "Highly dispersed palladium(II) in a defective metal-organic framework: Application to C-H activation and functionalization". . p. 20138 - 20141. Retrieved 2011.
• 6、 Zeynizadeh, Behzad,Mousavi, Hossein,Sepehraddin, Farhad. "A green and efficient Pd-free protocol for the Suzuki–Miyaura cross-coupling reaction using Fe3O4@APTMS@Cp2ZrClx(x = 0, 1, 2) MNPs in PEG-400". . p. 3361 - 3382. Retrieved 2020.
• 7、 Patil, Aniruddha B.,Patil, Dinkar S.,Bhanage, Bhalchandra M.. "Selective and efficient synthesis of decahedral palladium nanoparticles and its catalytic performance for Suzuki coupling reaction". . p. 146 - 153. Retrieved 2012.
• 8、 Kulomzina et al.. "". . . Retrieved 1977.
• 9、 Masteri-Farahani, Majid,Niakan, Mahsa. "Pd–Ni bimetallic catalyst supported on dendrimer-functionalized magnetic graphene oxide for efficient catalytic Suzuki-Miyaura coupling reaction". . . Retrieved 2022/01/26.
• 10、 Liang, Tongling,Lin, Wenhua,Ma, Yanping,Sun, Wen-Hua,Zhang, Liping. "Sterically enhanced 2-iminopyridylpalladium chlorides as recyclable ppm-palladium catalyst for Suzuki–Miyaura coupling in aqueous solution". . . Retrieved 2021/10/20.