Stannane, [4-(1,1-dimethylethyl)cyclohexyl]triphenyl-, trans-

Base Information

Chemical Name:Stannane, [4-(1,1-dimethylethyl)cyclohexyl]triphenyl-, trans-
CAS No.:91280-87-4
Molecular Formula:C₂₈H₃₄Sn
Molecular Weight:489.288
Hs Code.:

Synonyms:

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Chemical Property of Stannane, [4-(1,1-dimethylethyl)cyclohexyl]triphenyl-, trans-

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Technology Process of Stannane, [4-(1,1-dimethylethyl)cyclohexyl]triphenyl-, trans-

There total 4 articles about Stannane, [4-(1,1-dimethylethyl)cyclohexyl]triphenyl-, trans- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: p-tert.-Butyl-cyclohexylmagnesiumbromid

: 639-58-7
triphenyltin chloride

: 91280-87-4
(trans-4-(tert-butyl)cyclohexyl)triphenylstannane

Guidance literature:: byproducts: (CH3)3CC6H10(cyclo)C6H10(cyclo)C(CH3)3; refluxing for 1 h, stirring at room temp. for 3 days; several crystn. (pentane), recrystn. (ethanol); elem. anal.; NMR;
DOI:10.1021/om00089a013

Reference yield:

: 16133-41-8
cis-1-(tert-butyl)-4-iodocyclohexane

: 639-58-7
triphenyltin chloride

: 91280-87-4
(trans-4-(tert-butyl)cyclohexyl)triphenylstannane

: 91280-88-5
(cis-4-(tert-butyl)cyclohexyl)triphenylstannane

Guidance literature:: cis-1-(tert-butyl)-4-iodocyclohexane; With tert.-butyl lithium; In diethyl ether; hexane; at -100 ℃; Schlenk technique; Inert atmosphere;

triphenyltin chloride; In diethyl ether; hexane; at -100 ℃; for 0.0833333h; Overall yield = 52 %; Overall yield = 127 mg; stereospecific reaction; Schlenk technique; Inert atmosphere;
DOI:10.1002/chem.201204076

Reference yield:

: 21862-63-5
trans-4-tert-butylcyclohexanol

: 91280-87-4
(trans-4-(tert-butyl)cyclohexyl)triphenylstannane

: 91280-88-5
(cis-4-(tert-butyl)cyclohexyl)triphenylstannane

Guidance literature:: Multi-step reaction with 2 steps

1.1: iodine; triphenylphosphine; 1-methyl-1H-imidazole / dichloromethane / 15 h / 0 °C / Schlenk technique; Inert atmosphere

2.1: tert.-butyl lithium / hexane; diethyl ether / -100 °C / Schlenk technique; Inert atmosphere

2.2: 0.08 h / -100 °C / Schlenk technique; Inert atmosphere

With 1-methyl-1H-imidazole; iodine; tert.-butyl lithium; triphenylphosphine; In diethyl ether; hexane; dichloromethane;
DOI:10.1002/chem.201204076