(Buta-1,3-diene-2,3-diyl)bis(trimethylstannane)

Base Information

Chemical Name:(Buta-1,3-diene-2,3-diyl)bis(trimethylstannane)
CAS No.:91312-27-5
Molecular Formula:C10H22Sn2
Molecular Weight:379.705
Hs Code.:
DSSTox Substance ID:DTXSID90529457

Synonyms:91312-27-5;(Buta-1,3-diene-2,3-diyl)bis(trimethylstannane);DTXSID90529457;2,3-BIS(TRIMETHYLSTANNYL)-1,3-BUTADIENE

Suppliers and Price of (Buta-1,3-diene-2,3-diyl)bis(trimethylstannane)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
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Total 0 raw suppliers

Chemical Property of (Buta-1,3-diene-2,3-diyl)bis(trimethylstannane)

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:379.97596
Heavy Atom Count:12
Complexity:177

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Sn](C)(C)C(=C)C(=C)[Sn](C)(C)C

Technology Process of (Buta-1,3-diene-2,3-diyl)bis(trimethylstannane)

There total 1 articles about (Buta-1,3-diene-2,3-diyl)bis(trimethylstannane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

: 917-54-4
methyllithium

: 91312-27-5
2,3-Bis(trimethylstannyl)-1,3-butadiene

: 149286-75-9
(CH₃)3SiCH₂CCCH₂(CH₃)3Sn

: 91312-28-6
2-(trimethylsilyl)-3-(trimethylstannyl)-1,3-butadiene

: 21752-78-3
1,4-bis(trimethylsilyl)-2-butyne

: 91312-26-4,91312-27-5
1,4-bis(trimethylstannyl)-2-butyne

Guidance literature:: With chloro-trimethyl-silane; In tetrahydrofuran; diethyl ether; pentane; N2; MeI in ether added to THF soln. if Sn-compound at -78°C; warmed to -40°C; after 1.5 h cooled to -78°C; Me3SiCl in pentane added; 5 min;; KOH added; poured into water; extd. with ether/pentane; organic layer washed with water and brine; filtered through Na2SO4; 3-t-butyl-4-hydroxy-5-methylphenyl sulfide added; solvent evapd.; distd.;;
DOI:10.1021/ja00068a020

Reference yield: 74.0%

: 917-54-4
methyllithium

: 91312-27-5
2,3-Bis(trimethylstannyl)-1,3-butadiene

: magnesium bromide ethyl etherate

: 882-33-7
diphenyldisulfane

: 91312-30-0
2-phenylthio-3-trimethylstannyl-1,3-butadiene

Guidance literature:: In tetrahydrofuran; diethyl ether; benzene; N2; MeLi in ether added to diene in THF at -78°C, after 2 min MgBr2*OEt2 in ether/benzene; poured into Ph2S2 in THF at -78°C; bath removed; stirred for 2.25 h;; poured into NaOH and ether/pentane; organic layer washed with water and brine; filtered through Na2SO4; radical inhibitor added; solvent removed; preparative TLC (50/1 pentane/ether);;
DOI:10.1021/ja00068a020

Reference yield: 16.0%

: 917-54-4
methyllithium

: 91312-27-5
2,3-Bis(trimethylstannyl)-1,3-butadiene

: 149286-75-9
(CH₃)3SiCH₂CCCH₂(CH₃)3Sn

: 91312-28-6
2-(trimethylsilyl)-3-(trimethylstannyl)-1,3-butadiene

: 21752-78-3
1,4-bis(trimethylsilyl)-2-butyne

: 91312-26-4,91312-27-5
1,4-bis(trimethylstannyl)-2-butyne

Guidance literature:: With chloro-trimethyl-silane; In tetrahydrofuran; diethyl ether; pentane; N2; MeI in ether added to THF soln. if Sn-compound at -78°C; warmed to -40°C; after 1.5 h cooled to -78°C; Me3SiCl in pentane added; 5 min;; KOH added; poured into water; extd. with ether/pentane; organic layer washed with water and brine; filtered through Na2SO4; 3-t-butyl-4-hydroxy-5-methylphenyl sulfide added; solvent evapd.; distd.;;
DOI:10.1021/ja00068a020