Trimethyl[3-(phenylsulfanyl)buta-1,3-dien-2-yl]stannane

Base Information

Chemical Name:Trimethyl[3-(phenylsulfanyl)buta-1,3-dien-2-yl]stannane
CAS No.:91312-30-0
Molecular Formula:C13H18SSn
Molecular Weight:325.062
Hs Code.:
DSSTox Substance ID:DTXSID50529458
Wikidata:Q82399886

Synonyms:91312-30-0;DTXSID50529458;Trimethyl[3-(phenylsulfanyl)buta-1,3-dien-2-yl]stannane

Suppliers and Price of Trimethyl[3-(phenylsulfanyl)buta-1,3-dien-2-yl]stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Trimethyl[3-(phenylsulfanyl)buta-1,3-dien-2-yl]stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:326.015124
Heavy Atom Count:15
Complexity:244

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Sn](C)(C)C(=C)C(=C)SC1=CC=CC=C1

Technology Process of Trimethyl[3-(phenylsulfanyl)buta-1,3-dien-2-yl]stannane

There total 1 articles about Trimethyl[3-(phenylsulfanyl)buta-1,3-dien-2-yl]stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 917-54-4
methyllithium

: 91312-27-5
2,3-Bis(trimethylstannyl)-1,3-butadiene

: magnesium bromide ethyl etherate

: 882-33-7
diphenyldisulfane

: 91312-30-0
2-phenylthio-3-trimethylstannyl-1,3-butadiene

Guidance literature:: In tetrahydrofuran; diethyl ether; benzene; N2; MeLi in ether added to diene in THF at -78°C, after 2 min MgBr2*OEt2 in ether/benzene; poured into Ph2S2 in THF at -78°C; bath removed; stirred for 2.25 h;; poured into NaOH and ether/pentane; organic layer washed with water and brine; filtered through Na2SO4; radical inhibitor added; solvent removed; preparative TLC (50/1 pentane/ether);;
DOI:10.1021/ja00068a020