BenzeneMethanethiol, sodiuM salt

Base Information

• Chemical Name: BenzeneMethanethiol, sodiuM salt
• CAS No.: 3492-64-6
• Molecular Formula: C7H8 S . Na
• Molecular Weight: 146.188
• Mol file: 3492-64-6.mol

Synonyms:Benzenemethanethiol,sodium salt (9CI); Sodium, (benzylthio)- (7CI); a-Toluenethiol, sodium salt (8CI); Benzyl mercaptan sodiumsalt; Phenylmethanethiol sodium salt; Sodium benzenemethanethiolate; Sodiumbenzylmercaptide; Sodium benzylthiolate; Sodium phenylmethanethiolate; Sodium a-toluenethiolate

Chemical Property of BenzeneMethanethiol, sodiuM salt

Chemical Property:

• Boiling Point: 181.1°Cat760mmHg
• Flash Point: 71.1°C
• PSA: 38.80000
• Density: 0.913g/cm³
• LogP: 2.11640

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BenzeneMethanethiol, sodiuM salt

There total 4 articles about BenzeneMethanethiol, sodiuM salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

phenylmethanethiol (100-53-8) → sodium benzylmercaptide (3492-64-6)

Guidance literature:

With sodium methylate; In methanol; at 20 ℃; Inert atmosphere; Green chemistry;

DOI:10.1080/17415993.2020.1856849

Reference yield:

sodium (7440-23-5) + phenylmethanethiol (100-53-8) → sodium benzylmercaptide (3492-64-6)

Guidance literature:

In diethyl ether; at 40 ℃; for 12h;

Reference yield:

1-[(4-methylphenyl)sulfonyl]-4-piperidinol ester + phenylmethanethiol (100-53-8) → sodium benzylmercaptide (3492-64-6)

Guidance literature:

In N-methyl-acetamide; chloroform;

upstream raw materials:

phenylmethanethiol

(2,9-dimethylphenanthroline) zinc bis(benzylmercaptonate)

disodium p-xylene-α,α'-dithiolate

sodium

Downstream raw materials:

2-benzylsulfanyl-1-phenylethan-1-ol

dithiocarbonic acid S-benzyl ester-S'-(4-chloro-benzyl ester)

{[2-(benzylsulfanyl)ethyl]sulfonyl}benzene

benzyl 2-quinolyl sulfide

Refernces

• 1、 Jardim, Guilherme A. M.,Oliveira, Willian X. C.,De Freitas, Rossimiriam P.,Menna-Barreto, Rubem F. S.,Silva, Thaissa L.,Goulart, Marilia O. F.,Da Silva Júnior, Eufranio N.. "Direct sequential C-H iodination/organoyl-thiolation for the benzenoid A-ring modification of quinonoid deactivated systems: A new protocol for potent trypanocidal quinones". supporting information. p. 1686 - 1691. Retrieved 2018/03/21.
• 2、 Galardon, Erwan,Daguet, Hombeline,Deschamps, Patrick,Roussel, Pascal,Tomas, Alain,Artaud, Isabelle. "Influence of the diamine on the reactivity of thiosulfonato ruthenium complexes with hydrosulfide (HS-)". . p. 2817 - 2821. Retrieved 2013/04/10.