chloro(chloromethyl)mercury

Base Information

• Chemical Name: chloro(chloromethyl)mercury
• CAS No.: 17305-95-2
• Molecular Formula: CH2 Cl2 Hg
• Molecular Weight: 285.523
• Mol file: 17305-95-2.mol

Synonyms:(Chloromethyl)mercurychloride (6CI); Methane, chloro-, mercury complex

Chemical Property of chloro(chloromethyl)mercury

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of chloro(chloromethyl)mercury

There total 6 articles about chloro(chloromethyl)mercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

mercuric(II) nitrate monohydrate + (H2O)5Cr(CH2Cl)(2+) (17477-09-7) → (chloromethyl)mercury(II) chloride (17305-95-2)

Guidance literature:

DOI:10.1039/J19680000034

Reference yield:

N-methyl-N-nitrosotoluene-p-sulfonamide (80-11-5) + mercury dichloride → (chloromethyl)mercury(II) chloride (17305-95-2)

Guidance literature:

With potassium hydroxide; In methanol; diethyl ether; byproducts: N2; addn. of MeOH to KOH (65°C), dropwise addn. of diazald in ether, refluxing), addn. of suspn. of HgCl2 in ether (0°C, ice-bath), pptn.; removal of solvent (evapn.), recrystn. (MeOH); elem. anal.;

DOI:10.1016/0584-8539(86)80034-4

Reference yield:

1-(chloromethyl)silatrane (42003-39-4) + mercury dichloride → (chloromethyl)mercury(II) chloride (17305-95-2)

Guidance literature:

In [⁽²⁾H₆]acetone; byproducts: ClSi(OCH2CH2)3N; not isolated, reaction followed by (1)H-NMR spectroscopy; Kinetics;

DOI:10.1016/0022-328X(85)80362-4

upstream raw materials:

1-(chloromethyl)silatrane

(H₂O)5Cr(CH₂Cl)⁽²⁺⁾

N-methyl-N-nitrosotoluene-p-sulfonamide

dichloro(2,2,N,N-tetramethylbut-3-enylamine)palladium(II)

Downstream raw materials:

Chloroiodomethane

Refernces

• 1、 Dodd,Johnson. "". . p. 34. Retrieved 1968.
• 2、 Nies, J. Dirk,Bellama, Jon M.,Ben-Zvi, Nava. "DIRECT TRANSFER OF ALIPHATIC AND AROMATIC SUBSTITUENTS FROM ORGANOSILATRANES TO MERCURY(II) SPECIES". . p. 315 - 320. Retrieved 2007/10/02.