(E)-1-Methoxy-2-(1-propenyl)benzene

Base Information

• Chemical Name: (E)-1-Methoxy-2-(1-propenyl)benzene
• CAS No.: 2077-36-3
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• Nikkaji Number: J141.459C,J510.871C
• Mol file: 2077-36-3.mol

Synonyms:(E)-1-Methoxy-2-(1-propenyl)benzene;2077-36-3;Benzene, 1-methoxy-2-(1-propenyl)-, (E)-;ghl.PD_Mitscher_leg0.479;SCHEMBL1883472;1-(1-Propenyl)-2-methoxybenzene;(e)-(prop-1-en-1-yl)methoxybenzene;1-Methoxy-2-[(E)-1-propenyl]benzene

Chemical Property of (E)-1-Methoxy-2-(1-propenyl)benzene

Chemical Property:

• Vapor Pressure: 0.149mmHg at 25°C
• Melting Point: 242-243 °C(Solv: tetrahydrofuran (109-99-9))
• Boiling Point: 222.7°Cat760mmHg
• Flash Point: 81.7°C
• PSA: 9.23000
• Density: 0.959g/cm³
• LogP: 2.72830
• XLogP3: 2.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 148.088815002
• Heavy Atom Count: 11
• Complexity: 129

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=CC1=CC=CC=C1OC
• Isomeric SMILES: C/C=C/C1=CC=CC=C1OC

Technology Process of (E)-1-Methoxy-2-(1-propenyl)benzene

There total 23 articles about (E)-1-Methoxy-2-(1-propenyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1-(o-methoxyphenyl)-1-propanol (7452-01-9) → (E)-1-(2-methoxyphenyl)prop-1-ene (2077-36-3)

Guidance literature:

With chloro-trimethyl-silane; dimethyl sulfoxide; In acetonitrile; at 50 ℃;

Reference yield: 90.0%

2-allylanisole (3698-28-0) → (E)-1-(2-methoxyphenyl)prop-1-ene (2077-36-3)

Guidance literature:

With potassium hydroxide semihydrate; hydroquinone; In water; dimethyl sulfoxide; at 100 ℃; for 2h; Inert atmosphere;

DOI:10.1007/s11172-012-0246-8

Reference yield: 83.0%

2-bromoanisole (578-57-4) + (E)-propenylboronic acid (6336-44-3,7547-96-8,88982-39-2,7547-97-9) → (E)-1-(2-methoxyphenyl)prop-1-ene (2077-36-3)

Guidance literature:

With potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In 1,2-dimethoxyethane; water; for 18h; Heating;

DOI:10.1021/jo800941h

upstream raw materials:

2-allylanisole

1-(o-methoxyphenyl)-1-propanol

(1RS,2RS)-2-diphenylphosphinoyl-1-(2-methoxyphenyl)propan-1-ol

(1RS,2SR)-2-diphenylphosphinoyl-1-(2-methoxyphenyl)propan-1-ol

Downstream raw materials:

(d,l)-2-methoxyamphetamine

1-Methoxy-2-(1-methoxy-propyl)-benzene

Acetic acid 1-(2-methoxy-phenyl)-propyl ester

1-(2-methoxyphenyl)propan-1-one