4,4'-Diiodo-3,3'-dimethoxybiphenyl

Base Information

• Chemical Name: 4,4'-Diiodo-3,3'-dimethoxybiphenyl
• CAS No.: 92160-61-7
• Molecular Formula: C14H12I2O2
• Molecular Weight: 466.057
• European Community (EC) Number: 660-907-8
• Nikkaji Number: J1.192.078K
• Mol file: 92160-61-7.mol

Synonyms:4,4'-diiodo-3,3'-dimethoxybiphenyl;92160-61-7;1-iodo-4-(4-iodo-3-methoxyphenyl)-2-methoxybenzene;1,1'-Biphenyl, 4,4'-diiodo-3,3'-dimethoxy-;SCHEMBL4307124;C14H12I2O2;3,3'-Dimethoxy-4,4'-diiodobiphenyl;AKOS005216646;4,4'-Diiodo-3,3'-dimethoxy-1,1'-biphenyl;1,1'-Biphenyl,4,4'-diiodo-3,3'-dimethoxy-

Chemical Property of 4,4'-Diiodo-3,3'-dimethoxybiphenyl

Chemical Property:

• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 465.89267
• Heavy Atom Count: 18
• Complexity: 236

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=C(C=CC(=C1)C2=CC(=C(C=C2)I)OC)I

Technology Process of 4,4'-Diiodo-3,3'-dimethoxybiphenyl

There total 1 articles about 4,4'-Diiodo-3,3'-dimethoxybiphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

Fast Blue B salt → 3,3'-dimethoxybiphenyl (6161-50-8) + 4,4'-diiodo-3,3'-dimethoxylbiphenyl (92160-61-7) + 4-iodo-3,3'-dimethoxy-1,1'-biphenyl (108541-94-2)

Guidance literature:

With potassium iodide; In water; at 20 ℃; for 12h;

DOI:10.1134/S1070363218100249

Reference yield: 77.0%

4,4'-diiodo-3,3'-dimethoxylbiphenyl (92160-61-7) + C14H15BO4 (195737-41-8) → 3,2',2'',2''',2'''',3'''''-Hexamethoxy-[1,4';1',1'';4'',4''';1''',1'''';4'''',1''''']sexiphenyl (195737-39-4)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate;

DOI:10.1021/ja971513h

Reference yield: 70.0%

4,4'-diiodo-3,3'-dimethoxylbiphenyl (92160-61-7) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → 4,4'-bis(4,4,5,5-tetramethyl-[1,3,2]-dioxaborolan-2-yl)-3,3'-dimethoxybiphenyl (256387-75-4)

Guidance literature:

(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride;

DOI:10.1039/b512276g

Downstream raw materials:

4,4'-Bis-(1-hydroxy-4-phenyl-cyclohexyl)-3,3'-dimethoxy-biphenyl

4,4'-Bis-(α-hydroxy-benzhydryl)-3,3'-dimethoxy-biphenyl

4,4'-Bis-(1-hydroxy-cyclohexyl)-3,3'-dimethoxy-biphenyl

3,5'-dimethoxy-4,4'-biphenoquinone