3-methyl-3,4-dihydro-2H-1,4-benzoxazine

Base Information

Chemical Name:3-methyl-3,4-dihydro-2H-1,4-benzoxazine
CAS No.:32329-20-7
Deprecated CAS:113708-92-2
Molecular Formula:C₉H₁₁NO
Molecular Weight:149.192
Hs Code.:2934999090
European Community (EC) Number:820-169-1
UNII:LG21YE3V7L
DSSTox Substance ID:DTXSID8044915
Nikkaji Number:J1.161.513I
ChEMBL ID:CHEMBL3183910
Mol file:32329-20-7.mol

Synonyms:3-methyl-3,4-dihydro-2H-1,4-benzoxazine;32329-20-7;3-Methyl-3,4-dihydro-2H-benzo[b][1,4]oxazine;2H-1,4-Benzoxazine, 3,4-dihydro-3-methyl-;UNII-LG21YE3V7L;LG21YE3V7L;3,4-dihydro-3-methyl-2H-1,4-benzoxazine;DTXSID8044915;3-METHYL-3,4-DIHYDRO-2H-BENZO[1,4]OXAZINE;SCHEMBL1146635;CHEMBL3183910;DTXCID6024915;BSDVKBWLRCKPFB-UHFFFAOYSA-N;BCP14442;Tox21_301241;MFCD01935996;AKOS005070238;3J-356S;AB10564;2,3-dihydro-3-methyl-1,4-benzoxazine;NCGC00256302-01;AM803695;CAS-32329-20-7;CS-0037800;FT-0680283;EN300-93875;(rs)-3-methyl-3,4-dihydro-2h-[1,4]benzoxazine;A875649;(RS)-3-Methyl-3,4-dihydro-2H-benzo[1,4]oxazine;J-512847;F1905-6501;Z1201621516

Suppliers and Price of 3-methyl-3,4-dihydro-2H-1,4-benzoxazine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
3-Methyl-3,4-dihydro-2H-1,4-benzoxazine
100mg
$ 155.00

TRC
3-Methyl-3,4-dihydro-2H-1,4-benzoxazine
10mg
$ 45.00

Oakwood
3-Methyl-3,4-dihydro-2H-1,4-benzoxazine 85%
1g
$ 205.00

Matrix Scientific
3-Methyl-3,4-dihydro-2H-1,4-benzoxazine >95%
500mg
$ 145.00

Matrix Scientific
3-Methyl-3,4-dihydro-2H-1,4-benzoxazine >95%
1g
$ 224.00

Matrix Scientific
3-Methyl-3,4-dihydro-2H-1,4-benzoxazine >95%
5g
$ 783.00

Crysdot
3-Methyl-3,4-dihydro-2H-benzo[b][1,4]oxazine 95+%
5g
$ 775.00

Chemenu
3-Methyl-3,4-dihydro-2H-benzo[b][1,4]oxazine 95%
5g
$ 732.00

American Custom Chemicals Corporation
3-METHYL-3,4-DIHYDRO-2H-1,4-BENZOXAZINE 95.00%
1G
$ 823.44

American Custom Chemicals Corporation
3-METHYL-3,4-DIHYDRO-2H-1,4-BENZOXAZINE 95.00%
5G
$ 1463.85

Total 21 raw suppliers

Chemical Property of 3-methyl-3,4-dihydro-2H-1,4-benzoxazine

Chemical Property:

Vapor Pressure:0.0171mmHg at 25°C
Melting Point:98-100°C
Boiling Point:216.7°Cat760mmHg
PKA:4.44±0.40(Predicted)
Flash Point:62.2°C
PSA：21.26000
Density:1.078g/cm³
LogP:2.01740
Storage Temp.:Keep in dark place,Sealed in dry,Room Temperature
XLogP3:2.1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:149.084063974
Heavy Atom Count:11
Complexity:138

Purity/Quality:

97% ^*data from raw suppliers

3-Methyl-3,4-dihydro-2H-1,4-benzoxazine ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1COC2=CC=CC=C2N1

Technology Process of 3-methyl-3,4-dihydro-2H-1,4-benzoxazine

There total 20 articles about 3-methyl-3,4-dihydro-2H-1,4-benzoxazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 5330-66-5
1-(2-nitrophenoxy)-propan-2-one

: 32329-20-7,113708-92-2
(RS)-3-methyl-3,4-dihydro-2H-[1,4]benzoxazine

Guidance literature:: With hydrogen; sodium hydroxide; Amperkat SK Ni-Mo 3706 from HC Starck; In methanol; toluene; at 40 ℃; for 1h; under 165017 Torr; pH=8 - 9; Product distribution / selectivity; Autoclave;

Reference yield: 92.0%

: 854666-04-9
1-(2-aminophenoxy)propan-2-ol

: 32329-20-7,113708-92-2
(RS)-3-methyl-3,4-dihydro-2H-[1,4]benzoxazine

Guidance literature:: With chloro(p-cymene)[(S)-2-(2-(diphenylphosphanyl)-phenyl)-4-phenyl-4,5-dihydrooxazole]ruthenium(II) chloride; potassium tert-butylate; In toluene; at 110 ℃; for 24h; Inert atmosphere;
DOI:10.1021/acscatal.6b00175