Technology Process of 6,11-Epoxy-5H-benzo[b]carbazole,
6,11-dihydro-6,11-dimethyl-5-(phenylsulfonyl)-
There total 12 articles about 6,11-Epoxy-5H-benzo[b]carbazole,
6,11-dihydro-6,11-dimethyl-5-(phenylsulfonyl)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
magnesium;
In
tetrahydrofuran;
for 4.5h;
Heating;
DOI:10.1021/jo00197a039
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1.) lithium diisopropylamide / 1.) 1.5h, -70 deg C to room temp., 2.) -70 deg C to room temp.
3: brown MnO2 / CHCl3 / 26 h / Heating
4: anhydrous Na2SO4, trifluoroacetic acid / CH2Cl2 / 0.92 h / Heating
5: 93 percent / magnesium metal / tetrahydrofuran / 4.5 h / Heating
With
manganese(IV) oxide; magnesium; sodium sulfate; trifluoroacetic acid; lithium diisopropyl amide;
In
tetrahydrofuran; dichloromethane; chloroform;
DOI:10.1021/jo00197a039
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 100 percent / N-bromosuccinimide / benzoyl peroxide / CCl4 / 2.5 h / Heating
2: 96 percent / H2O, sodium bicarbonate / tetrahydrofuran / 22.5 h
3: 99 percent / hexane; CH2Cl2 / 0.75 h / Heating
4: 93 percent / magnesium metal / tetrahydrofuran / 4.5 h / Heating
With
N-Bromosuccinimide; water; sodium hydrogencarbonate; magnesium;
dibenzoyl peroxide;
In
tetrahydrofuran; tetrachloromethane; hexane; dichloromethane;
DOI:10.1021/jo00197a039
