GALLIUM DICHLORIDE

Base Information

• Chemical Name: GALLIUM DICHLORIDE
• CAS No.: 86884-85-7
• Molecular Formula: Cl₄Ga₂
• Molecular Weight: 281.258
• Mol file: 86884-85-7.mol

Synonyms:

Chemical Property of GALLIUM DICHLORIDE

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of GALLIUM DICHLORIDE

There total 11 articles about GALLIUM DICHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

cis,trans-dichlorogallane dimer → gallium(I) tetrachlorogallate(III) (24597-12-4,86884-85-7)

Guidance literature:

In neat (no solvent); byproducts: H2; all manipulations under dry N2 or Ar; Ga compd. slowly heated to 150°C for 1 h in vac.; residue solidified at 20°C; elem. anal.;

DOI:10.1515/znb-2001-4-502

Reference yield:

gallium(II) chloride → gallium(III) chloride + gallium(III) chloride + GaGaCl4 (86884-85-7) + Gallium trichloride (13450-90-3)

Guidance literature:

In neat (no solvent, gas phase); heating to 445 K; identification by mass spectroscopy and electron diffraction;

DOI:10.1007/BF00746929

Reference yield:

Gallium trichloride (13450-90-3) → gallium(I) tetrachlorogallate(III) (24597-12-4,86884-85-7)

Guidance literature:

With Et₃SiH; In not given; redn. of GaCl3 with Et3SiH; according to Schmidt, E. S. et al. Naturforsch. 2001, 17b, 337-341;

DOI:10.1021/ic0201452

upstream raw materials:

gallium

Gallium trichloride

mercury(I) chloride

monochlorogallane

Downstream raw materials:

GaCl₂(4-methylpyridine)2(benzoato)*4-methylpyridine

Refernces

• 1、 Hay, Daniel N. T.,Swenson, Dale C.,Messerle, Louis. "Gallium and gallium dichloride, new solid-state reductants in preparative transition metal chemistry. New, lower temperature syntheses and convenient isolation of hexatantalum tetradecachloride octahydrate". . p. 4700 - 4707. Retrieved 2008/10/08.
• 2、 Johnsen,Downs,Goode,Greene,Himmel,Mueller,Parsons,Pulham. "Some chemical properties of monochlorogallane: Decomposition to gallium(I) trichlorogallate(III), Ga+[GaCl3H]-, and other reactions". . p. 4755 - 4761. Retrieved 2008/10/08.