Benzenemethanol, 2-[[(1E)-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-penten-1-yl]dimethylsil yl]-

Base Information

Chemical Name:Benzenemethanol, 2-[[(1E)-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-penten-1-yl]dimethylsil yl]-
CAS No.:926321-10-0
Molecular Formula:C20H36O2Si2
Molecular Weight:364.676
Hs Code.:

Synonyms:

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Chemical Property of Benzenemethanol, 2-[[(1E)-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-penten-1-yl]dimethylsil yl]-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Benzenemethanol, 2-[[(1E)-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-penten-1-yl]dimethylsil yl]-

There total 9 articles about Benzenemethanol, 2-[[(1E)-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-penten-1-yl]dimethylsil yl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 853955-58-5
dimethyl(2-(((tetrahydro-2H-pyran-2-yl)oxy)methyl)phenyl)silane

: 926321-10-0
(E)-5-tert-butyldimethylsiloxy-1-pentenyl[2-(hydroxymethyl)phenyl]dimethylsilane

Guidance literature:: Multi-step reaction with 5 steps

1: 83 percent / p-toluenesulfonic acid monohydrate / methanol / 16 h / 20 °C

2: LiAlH₄ / diethyl ether / 1.67 h / 20 °C

3: diethyl ether / 0 - 20 °C

4: (t-Bu)3P / Pt(1,3-divinyl-1,1,3,3-tetramethyldisiloxane) / hexane / 3 h / 20 °C

5: K₂CO₃ / methanol; H₂O / 50 °C

With lithium aluminium tetrahydride; tri-tert-butyl phosphine; potassium carbonate; toluene-4-sulfonic acid; Pt(1,3-divinyl-1,1,3,3-tetramethyldisiloxane); In methanol; diethyl ether; hexane; water;
DOI:10.1016/j.jorganchem.2006.04.046

Reference yield:

: 17100-66-2
2-(tetrahydropyranyloxy)methylbromobenzene

: 926321-10-0
(E)-5-tert-butyldimethylsiloxy-1-pentenyl[2-(hydroxymethyl)phenyl]dimethylsilane

Guidance literature:: Multi-step reaction with 6 steps

1.1: n-BuLi / tetrahydrofuran; hexane / 0.67 h / -78 °C

1.2: 83 percent / tetrahydrofuran; hexane / -78 - 20 °C

2.1: 83 percent / p-toluenesulfonic acid monohydrate / methanol / 16 h / 20 °C

3.1: LiAlH₄ / diethyl ether / 1.67 h / 20 °C

4.1: diethyl ether / 0 - 20 °C

5.1: (t-Bu)3P / Pt(1,3-divinyl-1,1,3,3-tetramethyldisiloxane) / hexane / 3 h / 20 °C

6.1: K₂CO₃ / methanol; H₂O / 50 °C

With lithium aluminium tetrahydride; n-butyllithium; tri-tert-butyl phosphine; potassium carbonate; toluene-4-sulfonic acid; Pt(1,3-divinyl-1,1,3,3-tetramethyldisiloxane); In tetrahydrofuran; methanol; diethyl ether; hexane; water;
DOI:10.1016/j.jorganchem.2006.04.046

Reference yield:

: 18982-54-2
o-bromobenzyl alcohol

: 926321-10-0
(E)-5-tert-butyldimethylsiloxy-1-pentenyl[2-(hydroxymethyl)phenyl]dimethylsilane

Guidance literature:: Multi-step reaction with 7 steps

1.1: conc. hydrochloric acid / 20 °C

2.1: n-BuLi / tetrahydrofuran; hexane / 0.67 h / -78 °C

2.2: 83 percent / tetrahydrofuran; hexane / -78 - 20 °C

3.1: 83 percent / p-toluenesulfonic acid monohydrate / methanol / 16 h / 20 °C

4.1: LiAlH₄ / diethyl ether / 1.67 h / 20 °C

5.1: diethyl ether / 0 - 20 °C

6.1: (t-Bu)3P / Pt(1,3-divinyl-1,1,3,3-tetramethyldisiloxane) / hexane / 3 h / 20 °C

7.1: K₂CO₃ / methanol; H₂O / 50 °C

With hydrogenchloride; lithium aluminium tetrahydride; n-butyllithium; tri-tert-butyl phosphine; potassium carbonate; toluene-4-sulfonic acid; Pt(1,3-divinyl-1,1,3,3-tetramethyldisiloxane); In tetrahydrofuran; methanol; diethyl ether; hexane; water;
DOI:10.1016/j.jorganchem.2006.04.046