Cyclopentanecarbaldehyde

Base Information

• Chemical Name: Cyclopentanecarbaldehyde
• CAS No.: 872-53-7
• Molecular Formula: C6H10O
• Molecular Weight: 98.1448
• Hs Code.: 29122990
• European Community (EC) Number: 212-829-7
• NSC Number: 17492
• DSSTox Substance ID: DTXSID10236176
• Nikkaji Number: J79.991B
• Wikidata: Q72460288
• ChEMBL ID: CHEMBL274711
• Mol file: 872-53-7.mol

Synonyms:Cyclopentanecarbaldehyde;872-53-7;Cyclopentanecarboxaldehyde;Cyclopentanealdehyde;Cyclopentylformaldehyde;MFCD00060798;CHEMBL274711;EINECS 212-829-7;cyclopentancarbaldehyd;Cyclopentanecarboxaldehyde (25ppm 1,4-Benzoquinone as stabiliser);Formylcyclopentane;Cyclopentyl aldehyde;NSC17492;cyclopentanecaboxaldehyde;cyclopentanecarboaldehyde;cyclopentane carbaldehyde;Cyclopentane-carboaldehyde;cyclopentane carboxaldehyde;Cyclopentanecarbaldehyde #;Cyclopentane-carboxaldehyde;Cyclopentane-1-carboxaldehyde;Cyclopentanecarboxaldehyde, 97%;DTXSID10236176;BCP12309;CS-B0070;BBL100156;BDBM50028792;NSC 17492;NSC-17492;STL512072;AKOS005259282;AB02400;AM83284;AS-16170;SY004589;C3019;FT-0648936;EN300-57255;H11353;W-104036;Z875036058;Cyclopentanecarbaldehyde, 0.1% hydroquinone as stabilizer

Chemical Property of Cyclopentanecarbaldehyde

Chemical Property:

• Appearance/Colour: clear colorless to light yellow liquid
• Vapor Pressure: 8.51mmHg at 25°C
• Refractive Index: n20/D 1.4430(lit.)
• Boiling Point: 133.3 °C at 760 mmHg
• Flash Point: 36 °C
• PSA: 17.07000
• Density: 1.029 g/cm³
• LogP: 1.37550
• Storage Temp.: Room temperature.
• Water Solubility.: Soluble in water and ethanol
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 98.073164938
• Heavy Atom Count: 7
• Complexity: 62.6

Purity/Quality:

99% ^*data from raw suppliers

Cyclopentanecarboxaldehyde ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 10-36/37/38
• Safety Statements: 16-26-36-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1CCC(C1)C=O
• Uses: Cyclopentanecarboxaldehyde may be used in the synthesis of:D,L-trans-2-cyclopentylmethylene-1-nitroso-1-(2-hydroxycyclohexyl)hydrazineethyl 5-cyclopentyl-5-hydroxy-2-pentenoateethyl 3-cyclo entyl-3-hydroxy-2-vinylpropanoate

Technology Process of Cyclopentanecarbaldehyde

There total 126 articles about Cyclopentanecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.5%

carbon monoxide (201230-82-2) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → cyclopentanealdehyde (872-53-7) + Cyclopentane (287-92-3)

Guidance literature:

With hydrogen; N-dodecyl-N-(2-hydroxyethyl)-N,N-dimethylammonium bromide; {Rh(cod)[μ-S(CH2)3Si(OMe)3]}2; triphenylphosphine; In water; butan-1-ol; at 80 ℃; for 15h; under 10350.8 Torr; microemulsion/sol-gel;

DOI:10.1002/ejoc.200500244

Reference yield: 2.0%

cyclohexene (110-83-8) → cyclopentanealdehyde (872-53-7) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) + Cyclohex-2-enol (822-67-3)

Guidance literature:

With dipotassium peroxodisulfate; copper(II) sulfate; In water; acetonitrile; at 60 ℃; for 6h;

Reference yield:

benzene-1,2-diol (120-80-9,19481-10-8,37349-32-9) → cyclopentanealdehyde (872-53-7) + 1-amino-cyclopentanemethanol (3637-61-4)

Guidance literature:

With water; In decane; at 250 ℃; for 1.41667h; under 30003 Torr;

DOI:10.1002/cctc.201500345

upstream raw materials:

Tetrahydropyran-2-methanol

phthalic anhydride

cyclohexane-1,2-epoxide

1-methyl-4-nitrosobenzene

Downstream raw materials:

1-cyclopentyl-3-phenyl-1-propanol

1,1-bis-(hydroxymethyl)cyclopentane

cyclopentyl(4-methoxyphenyl)methanol

4-Cyclopentylbut-3-en-2-on

Refernces

• 1、 Li, Chuanzhao,Chen, Li,Garland, Marc. "Synchronicity of mononuclear and dinuclear events in homogeneous catalysis. Hydroformylation of cyclopentene using Rh4(CO)12 and HRe(CO)5 as precursors". . p. 13327 - 13334. Retrieved 2007.
• 2、 Chen, Tao,Xu, Zhenkai,Zhou, Lei,Qiu, Jiaqi,Wang, Maolin,Wang, Jiping. "Highly efficient polymer-based nanoreactors for selective oxidation of alcohols in water". . . Retrieved 2019/05/28.
• 3、 Sun, Hao,Guo, Wanwan,Liu, Junmei,Feng, Zhipeng,Li, Ruyue,Zhou, Xuyang,Huang, Jun. "Supported rhodium liquid metal catalysts for the hydroformylation of olefins". . . Retrieved 2018/09/25.