Borane, dicyclohexyl(1-methyl-1-hexenyl)-, (E)-

Base Information

Chemical Name:Borane, dicyclohexyl(1-methyl-1-hexenyl)-, (E)-
CAS No.:92747-34-7
Molecular Formula:C₁₉H₃₅B
Molecular Weight:274.298
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Borane, dicyclohexyl(1-methyl-1-hexenyl)-, (E)-

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of Borane, dicyclohexyl(1-methyl-1-hexenyl)-, (E)-

There total 2 articles about Borane, dicyclohexyl(1-methyl-1-hexenyl)-, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 1119-64-8
1-bromohexyne

: 13283-31-3
borane

: 110-83-8
cyclohexene

: 90542-37-3
C₄H₉CHC(C₆H₁₁)B(CH₃)(C₆H₁₁)

: 92747-34-7
Dicyclohexyl-((E)-1-methyl-hex-1-enyl)-borane

Guidance literature:: With methyl magnesium iodide; In tetrahydrofuran; diethyl ether; under Ar, bromoalkenylborane prepd. by addn. of cyclohexene to BH3 in THF, 1-bromo-1-hexyne added slowly at -10°C, stirred for 3 h at 0°C, Et2O soln. of MeMgI added at -50°C, stirred at this temp. for 1 h, warmed to room temp.; not isolated; yields estimated from amt. of ketone after oxidn. with H2O2;
DOI:10.1246/bcsj.57.209

Reference yield:

: 1119-67-1
1-iodo-1-hexyne

: 1568-65-6
bis(cyclohexanyl)borane

: 90542-37-3
C₄H₉CHC(C₆H₁₁)B(CH₃)(C₆H₁₁)

: 92747-34-7
Dicyclohexyl-((E)-1-methyl-hex-1-enyl)-borane

Guidance literature:: With CH₃MgI or CH₃MgBr or CH₃MgCl; successive treatment of 1-iodo-1-hexyne with the borane at 0°C and with the Grignard reagent at -50°C;; 2 nd prod. separated by column chromy. or gas chromy.;;
DOI:10.1246/cl.1984.1029

Reference yield:

: 92747-34-7
Dicyclohexyl-((E)-1-methyl-hex-1-enyl)-borane

: 106-95-6
allyl bromide

: 92747-36-9
(Z)-4-Methyl-nona-1,4-diene

: ((E)-1-Allyl-hex-1-enyl)-cyclohexane

Guidance literature:: With sodium hydroxide; copper acetylacetonate; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, H₂O, RT; 0.5 h, 2.) THF, H₂O, -15 deg C, 1 h, 3.) THF, H₂O, RT; 20 h,;
DOI:10.1246/cl.1984.1029