1,4,7,10-Tetraoxacyclotridecane, 12-methylene-

Base Information

Chemical Name:1,4,7,10-Tetraoxacyclotridecane, 12-methylene-
CAS No.:92818-16-1
Molecular Formula:C₁₀H₁₈O₄
Molecular Weight:202.251
Hs Code.:
DSSTox Substance ID:DTXSID70465420
Wikidata:Q82291356

Synonyms:12-methylidene-1,4,7,10-tetraoxacyclotridecane;92818-16-1;1,4,7,10-Tetraoxacyclotridecane, 12-methylene-;DTXSID70465420;12-methylene-1,4,7,10-tetraoxacyclotridecane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,4,7,10-Tetraoxacyclotridecane, 12-methylene-

Chemical Property:

XLogP3:-0.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:202.12050905
Heavy Atom Count:14
Complexity:142

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C=C1COCCOCCOCCOC1

Technology Process of 1,4,7,10-Tetraoxacyclotridecane, 12-methylene-

There total 2 articles about 1,4,7,10-Tetraoxacyclotridecane, 12-methylene- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 107094-31-5
3-<(tosyloxy)methyl>-13-crown-4

: 107123-13-7
5-Decyl-2-(1,4,7,10-tetraoxa-cyclotridec-12-ylmethoxy)-benzoic acid methyl ester

: 92818-16-1
12-methylene-1,4,7,10-tetraoxacyclotridecane

Guidance literature:: With sodium hydride; In tetrahydrofuran; for 72h; Heating;

Reference yield:

: 107094-31-5
3-<(tosyloxy)methyl>-13-crown-4

: 87708-31-4
methyl 5-(n-decyl)salicylate

: 107123-13-7
5-Decyl-2-(1,4,7,10-tetraoxa-cyclotridec-12-ylmethoxy)-benzoic acid methyl ester

: 92818-16-1
12-methylene-1,4,7,10-tetraoxacyclotridecane

Guidance literature:: With sodium hydride; Yield given. Multistep reaction; 1.) THF, room temperature, 1 h; 2.) reflux, 72 h;

Reference yield: 68.0%

: 892-20-6
triphenylstannane

: 92818-16-1
12-methylene-1,4,7,10-tetraoxacyclotridecane

: 1242843-56-6
(1,4,7,10-tetraoxacyclotridec-12-ylmethyl)triphenylstannane

Guidance literature:: With AIBN; In neat (no solvent); (N2 or Ar); CH2C(CH2OC2H4OCH2)2 mixed with (C6H5)3SnH, AIBN added, stirred at 60-80°C for 15 h; cooled to room temp., CH2Cl2 added, filtered, evapd. (vac.), chromd. (silica gel/CH2Cl2, EtOH), solidified for days at room temp.; elem. anal.;
DOI:10.1021/om100409v