(1,4,7,10-tetraoxacyclotridec-12-ylmethyl)triphenylstannane

Base Information

• Chemical Name: (1,4,7,10-tetraoxacyclotridec-12-ylmethyl)triphenylstannane
• CAS No.: 1242843-56-6
• Molecular Formula: C₂₈H₃₄O₄Sn
• Molecular Weight: 553.286
• Mol file: 1242843-56-6.mol

Synonyms:

Chemical Property of (1,4,7,10-tetraoxacyclotridec-12-ylmethyl)triphenylstannane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,4,7,10-tetraoxacyclotridec-12-ylmethyl)triphenylstannane

There total 1 articles about (1,4,7,10-tetraoxacyclotridec-12-ylmethyl)triphenylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

triphenylstannane (892-20-6) + 12-methylene-1,4,7,10-tetraoxacyclotridecane (92818-16-1) → (1,4,7,10-tetraoxacyclotridec-12-ylmethyl)triphenylstannane (1242843-56-6)

Guidance literature:

With AIBN; In neat (no solvent); (N2 or Ar); CH2C(CH2OC2H4OCH2)2 mixed with (C6H5)3SnH, AIBN added, stirred at 60-80°C for 15 h; cooled to room temp., CH2Cl2 added, filtered, evapd. (vac.), chromd. (silica gel/CH2Cl2, EtOH), solidified for days at room temp.; elem. anal.;

DOI:10.1021/om100409v

Reference yield: 90.0%

(1,4,7,10-tetraoxacyclotridec-12-ylmethyl)triphenylstannane (1242843-56-6) + bromine (7726-95-6) → bromido(1,4,7,10-tetraoxacyclotridec-12-ylmethyl)diphenylstannane (1430805-36-9)

Guidance literature:

In dichloromethane; at -55 - 20 ℃; for 15h;

DOI:10.1021/om400216z

Reference yield: 82.0%

(1,4,7,10-tetraoxacyclotridec-12-ylmethyl)triphenylstannane (1242843-56-6) + iodine (7553-56-2,12190-71-5,8031-47-8) → diiodido(1,4,7,10-tetraoxacyclotridec-12-ylmethyl)phenylstannane

Guidance literature:

In dichloromethane; byproducts: C6H5I; (N2 or Ar); I2 added over a period of 3 h at 0°C to a soln. of Sncompd., stirred and warmed to room temp. overnight; evapd. (vac.), recrystd. from EtOH -5°C; elem. anal.;

DOI:10.1021/om100409v

upstream raw materials:

triphenylstannane

12-methylene-1,4,7,10-tetraoxacyclotridecane

Downstream raw materials:

iodido(1,4,7,10-tetraoxacyclotridec-12-ylmethyl)diphenylstannane

trichlorido(1,4,7,10-tetraoxacyclotridec-12-ylmethyl)stannane

bromido(1,4,7,10-tetraoxacyclotridec-12-ylmethyl)diphenylstannane

hydrido(1,4,7,10-tetraoxacyclotridec-12-ylmethyl)diphenylstannane