3-phenoxycycliccarbonate ;;

Base Information

• Chemical Name: 3-phenoxycycliccarbonate
• CAS No.: 4437-83-6
• Molecular Formula: C₁₀H₁₀O₄
• Molecular Weight: 194.187
• Mol file: 4437-83-6.mol

Synonyms:

Chemical Property of 3-phenoxycycliccarbonate ;;

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-phenoxycycliccarbonate ;;

There total 29 articles about 3-phenoxycycliccarbonate ;; which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

carbon dioxide (124-38-9,18923-20-1) + Phenyl glycidyl ether (122-60-1,71031-02-2) → 4-(phenoxy)methyl-1,3-dioxolane-2-one (4437-83-6)

Guidance literature:

With 1-methyl-1H-imidazole; CrTTPCl; at 70 ℃; for 16h; under 40337.5 Torr;

DOI:10.1021/jo00108a042

Reference yield: 91.0%

carbon dioxide (124-38-9,18923-20-1) + 1-bromo-3-phenoxy-propan-2-ol (140428-44-0,140630-35-9,140630-39-3,95302-24-2) + 1,2-Epoxy-3-bromopropane (3132-64-7,82584-73-4) → 4-(phenoxy)methyl-1,3-dioxolane-2-one (4437-83-6) + 1,3-dibromo-2-hydroxypropane (96-21-9)

Guidance literature:

1-bromo-3-phenoxy-propan-2-ol; 1,2-Epoxy-3-bromopropane; With C₁₈H₂₃N₂O₄⁽¹⁺⁾*Br^(1-); at 60 ℃; for 2h; Autoclave;

carbon dioxide; at 60 ℃; for 4h; under 7500.75 Torr; Autoclave;

DOI:10.1002/ejoc.201601315

Reference yield: 90.0%

3-phenoxy-1,2-propanediol (538-43-2) + ethyl isocyanate (109-90-0) → 4-(phenoxy)methyl-1,3-dioxolane-2-one (4437-83-6)

Guidance literature:

3-phenoxy-1,2-propanediol; ethyl isocyanate; In dichloromethane; Heating;

With 3 A molecular sieve; acetic acid; sodium nitrite; at 80 ℃; for 15h;

DOI:10.1246/bcsj.77.1217

upstream raw materials:

4-chloromethyl-[1,3]dioxolan-2-one

phenol

β-Propiolactone

Phenyl glycidyl ether

Downstream raw materials:

3-phenoxy-2-hydroxypropyl-N-2-hydroxyethylurethane

Dibutyl-carbamic acid 2-hydroxy-3-phenoxy-propyl ester

Methyl-carbamic acid 2-hydroxy-3-phenoxy-propyl ester

3-phenoxy-1,2-propanediol

Refernces

• 1、 Xie, Haibo,Duan, Haifeng,Li, Shenghai,Zhang, Suobo. "The effective synthesis of propylene carbonate catalyzed by silica-supported hexaalkylguanidinium chloride". . p. 1199 - 1203. Retrieved 2005.
• 2、 Bai, Dongsheng,Jing, Huanwang,Wang, Guangjian. "Cyclic carbonate synthesis from epoxides and CO2 over cyanocobalamin/n-Bu4NI". . p. 600 - 603. Retrieved 2012.
• 3、 Magnuson, Zachary L.,Cheng, Qigan,Zhang, Weijie,Chen, Yu-Sheng,Wojtas, Lukasz,Nafady, Ayman,Al-Enizi, Abdullah M.,Larsen, Randy W.,Zhang, X. Peter,Ma, Shengqian. "Two Manganese Metalloporphyrin Frameworks Constructed from a Custom-Designed Porphyrin Ligand Exhibiting Selective Uptake of CO2over CH4and Catalytic Activity for CO2Fixation". . p. 2786 - 2792. Retrieved 2021.
• 4、 Jose, Tharun,Hwang, Yeseul,Kim, Dong-Woo,Kim, Moon-Il,Park, Dae-Won. "Functionalized zeolitic imidazolate framework F-ZIF-90 as efficient catalyst for the cycloaddition of carbon dioxide to allyl glycidyl ether". . p. 61 - 67. Retrieved 2015.
• 5、 Yue, Chengtao,Su, Dan,Zhang, Xu,Wu, Wei,Xiao, Linfei. "Amino-functional imidazolium ionic liquids for CO2 activation and conversion to form cyclic carbonate". . p. 1313 - 1321. Retrieved 2014.
• 6、 Sun, Yuxiu,Jia, Xuemeng,Huang, Hongliang,Guo, Xiangyu,Qiao, Zhihua,Zhong, Chongli. "Solvent-free mechanochemical route for the construction of ionic liquid and mixed-metal MOF composites for synergistic CO2 fixation". . p. 3180 - 3185. Retrieved 2020.
• 7、 Mamone, Marius,Milcent, Thierry,Crousse, Benoit. "Reactivity of carbon dioxide in hydrofluoroethers: A facile access to cyclic carbonates". . p. 12736 - 12739. Retrieved 2015.
• 8、 Gabov, I. S.,Kuznetsov, V. A.,Pestov, A. V.,Puzyrev, I. S.. "Addition of the oxirane derivatives to CO2 catalyzed by Lewis bases under mild conditions". . p. 1118 - 1123. Retrieved 2021.
• 9、 Kim, So Han,Ahn, Duseong,Go, Min Jeong,Park, Myung Hwan,Kim, Min,Lee, Junseong,Kim, Youngjo. "Dinuclear aluminum complexes as catalysts for cycloaddition of CO 2 to epoxides". . p. 2770 - 2775. Retrieved 2014.
• 10、 Gao, Jinbin,Lai, Shilin,Xiong, Xingquan. "Rosin-based porous heterogeneous catalyst functionalized with hydroxyl groups and triazole groups for CO2 chemical conversion under atmospheric pressure condition". . . Retrieved 2021/07/14.