2-(1-Chloro-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:2-(1-Chloro-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:94242-82-7
Molecular Formula:C14H20BClO2
Molecular Weight:266.576
Hs Code.:
DSSTox Substance ID:DTXSID70541531

Synonyms:94242-82-7;2-(1-chloro-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;SCHEMBL2123752;DTXSID70541531

Suppliers and Price of 2-(1-Chloro-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-(1-Chloro-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:266.1244877
Heavy Atom Count:18
Complexity:272

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C(CC2=CC=CC=C2)Cl

Technology Process of 2-(1-Chloro-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 13 articles about 2-(1-Chloro-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 75-09-2
dichloromethane

: 87100-28-5
pinacol benzylboronate

: 94242-82-7
2-(1-chloro-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: dichloromethane; With n-butyllithium; In tetrahydrofuran; hexane; at -100 ℃; for 0.75h;

pinacol benzylboronate; In tetrahydrofuran; hexane; at -100 - 20 ℃;
DOI:10.1021/acs.orglett.1c01213

Reference yield: 42.4%

: 94242-82-7
2-(1-chloro-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:

Reference yield:

: 1259299-79-0
2-(1-chloro-2-phenylvinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 165904-22-3
4,4,5,5-tetramethyl-2-phenethyl-1,3,2-dioxaborolane

: 94242-82-7
2-(1-chloro-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With Crabtree's catalyst; hydrogen; In dichloromethane; at 50 ℃; for 12h; under 7500.75 Torr; chemoselective reaction;
DOI:10.1002/anie.201106262