Dichloro-pi-cyclopentadienyl(trimethylsilyl-pi-cyclopentadienyl)titanium

Base Information

Chemical Name:Dichloro-pi-cyclopentadienyl(trimethylsilyl-pi-cyclopentadienyl)titanium
CAS No.:79269-70-8
Molecular Formula:C13H18Cl2SiTi
Molecular Weight:321.157
Hs Code.:

Synonyms:Dichloro-pi-cyclopentadienyl(trimethylsilyl-pi-cyclopentadienyl)titanium;Titanium, dichloro-pi-cyclopentadienyl(trimethylsilyl-pi-cyclopentadienyl)-;eta(sup 5)-Trimethylsilylcyclopentadienyl-eta(sup 5)-cyclopentadienyl-dichlorotitan(IV);79269-70-8;C13H18Cl2SiTi;C13-H18-Cl2-Si-Ti;LS-153908

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Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Dichloro-pi-cyclopentadienyl(trimethylsilyl-pi-cyclopentadienyl)titanium

Chemical Property:

Vapor Pressure:4.95mmHg at 25°C
Boiling Point:150.2°Cat760mmHg
Flash Point:29.7°C
Density:g/cm³
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:1
Exact Mass:320.003423
Heavy Atom Count:17
Complexity:96.8

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)C1=C[CH-]C=C1.[CH-]1C=CC=C1.[Cl-].[Cl-].[Ti+4]

Technology Process of Dichloro-pi-cyclopentadienyl(trimethylsilyl-pi-cyclopentadienyl)titanium

There total 2 articles about Dichloro-pi-cyclopentadienyl(trimethylsilyl-pi-cyclopentadienyl)titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1270-98-0
cyclopentadienyl titanium(IV) trichloride

: 1271-19-8
bis(cyclopentadienyl)titanium dichloride

: 59307-41-4
bis(η5-trimethylsilylcyclopentadienyl)titanium(IV)dichloride

: 79269-70-8
dichloro(η⁵-cyclopentadienyl)[η⁵-(trimethylsilyl)cyclopentadienyl]titanium

Guidance literature:: With C₅H₅SiMe₃; C₄H₉Li; In tetrahydrofuran; hexane; under N2; adding 2.5 M nBuLi in hexane to THF soln. of C5H5SiMe3 at -70°C, stirring for 5 min, warming within 1 h to 25°C, heatingto reflux for 5 min, cooling to 25°C, adding THF soln. of (C5H5) TiCl3, heating to reflux for 1 h; removal of volatiles in oil pump vac., extg. residue with CH2Cl2, filtering through SiO2, removal of solvents in oil pump vac.; elem. anal.;
DOI:10.1016/S0022-328X(01)01000-2

Reference yield: 76.0%

: 1270-98-0
cyclopentadienyl titanium(IV) trichloride

: lithium trimethylsilylcyclopentadienide

: 79269-70-8
dichloro(η⁵-cyclopentadienyl)[η⁵-(trimethylsilyl)cyclopentadienyl]titanium

Guidance literature:: In tetrahydrofuran; (C5H4Si(CH3)3)Li soln. added slowly to complex soln. under Ar at room temp., stirred for 30 min; evapd. (vac.), washed with aq. HCl, with EtOH, with ether, recrystd. (hot CHCl3/hexane);
DOI:10.1021/om00080a010

Reference yield: 78.0%

: 79269-70-8
dichloro(η⁵-cyclopentadienyl)[η⁵-(trimethylsilyl)cyclopentadienyl]titanium

: 536-74-3
phenylacetylene

: 380614-28-8
(η5-cyclopentadienyl)(η5-C5H4SiMe3)Ti(CCC6H5)2

Guidance literature:: With nBuLi; In tetrahydrofuran; diethyl ether; hexane; under N2; adding 2.5 M nBuLi in hexane in one portion to Et2O soln. of HCCC6H5 at -70°C, stirring for 5 min, warming to 25°C within 1 h, adding THF soln. of Ti complex in one portion, stirring at 25°C for 4 h; removal of volatiles in oil pump vac., filtration of residue in Et2O through SiO2, removal of solvents; elem. anal.;
DOI:10.1016/S0022-328X(01)01000-2