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(R)-methyl 2-chloropropanoate

Base Information Edit
  • Chemical Name:(R)-methyl 2-chloropropanoate
  • CAS No.:77287-29-7
  • Molecular Formula:C4H7 Cl O2
  • Molecular Weight:122.551
  • Hs Code.:29159000
  • European Community (EC) Number:278-658-5,625-379-5
  • UNII:89L56A505X
  • DSSTox Substance ID:DTXSID901032960
  • Nikkaji Number:J56.929A
  • Wikidata:Q27896156
  • Mol file:77287-29-7.mol
(R)-methyl 2-chloropropanoate

Synonyms:77287-29-7;(R)-methyl 2-chloropropanoate;Methyl (R)-(+)-2-chloropropionate;Methyl (R)-2-chloropropionate;methyl (2R)-2-chloropropanoate;(R)-(+)-2-Chloropropionic acid methyl ester;(R)-(+)-Methyl (R)-2-chloropropionate;CCRIS 7388;Propanoic acid, 2-chloro-, methyl ester, (2R)-;(R)-2-Chloropropanoic acid methyl ester;EINECS 278-658-5;(+)-Methyl (R)-2-chloropropionate;Methyl (R)-(-)-2-chloropropionate;Methyl 2-chloropropanoate, (R)-;89L56A505X;(R)-METHYL 2-CHLORO-PROPIONATE;(-)-Methyl (S)-2-chloropropionate;Methyl 2-chloropropanoate #;L(-)-2-Chloropropionate methyl ester;Methyl(R)-(+)-2-Chloropropionate;methyl (2R)-chloropropionate;SCHEMBL534023;(r)-methyl 2-chloropropionate;UNII-89L56A505X;DTXSID901032960;(R)-2-Chloropropionic acid methyl;methyl (2R)-2-chloranylpropanoate;MFCD00062940;AKOS015848430;(+)-METHYL 2-CHLOROPROPANOATE;AM81434;METHYL D-.ALPHA.-CHLOROPROPIONATE;(2R)-2-chloropropanoic acid methyl ester;(R)-2-Chloropropionic Acid methyl Ester;AS-37972;BP-11134;METHYL 2-CHLOROPROPANOATE, (+)-;(+)-Methyl (R)-2-chloropropionate, 98%;(S)-(+)-METHYL 2-CHLOROPROPIONATE;LS-188775;(+)-METHYL .ALPHA.-CHLOROPROPIONATE;A9782;C1633;Propanoic acid, 2-chloro-, methyl ester, (R)-;A812180;Q27896156

Suppliers and Price of (R)-methyl 2-chloropropanoate
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • TRC
  • Methyl (R)-(+)-2-Chloropropionate
  • 500mg
  • $ 65.00
  • TRC
  • Methyl (R)-(+)-2-Chloropropionate
  • 100mg
  • $ 45.00
  • TCI Chemical
  • Methyl (R)-(+)-2-Chloropropionate >98.0%(GC)
  • 5g
  • $ 109.00
  • SynQuest Laboratories
  • Methyl (R)-(+)-2-chloropropionate
  • 2 g
  • $ 176.00
  • Sigma-Aldrich
  • (+)-Methyl (R)-2-chloropropionate 98%
  • 5g
  • $ 102.00
  • Chem-Impex
  • (+)-Methyl(R)-2-chloropropionate,95%(Chiralpurity) 95%(Chiralpurity)
  • 5G
  • $ 103.04
  • Apolloscientific
  • Methyl (R)-(+)-2-Chloropropionate
  • 2g
  • $ 160.00
  • American Custom Chemicals Corporation
  • (R)-(+)-METHYL 2-CHLOROPROPIONATE 95.00%
  • 1G
  • $ 632.28
  • AK Scientific
  • (R)-(+)-2-Chloropropionicacidmethylester
  • 5g
  • $ 217.00
  • AHH
  • (R)-(+)-Methyl(R)-2-chloropropionate 98%
  • 50g
  • $ 376.00
Total 21 raw suppliers
Chemical Property of (R)-methyl 2-chloropropanoate Edit
Chemical Property:
  • Vapor Pressure:9.57mmHg at 25°C 
  • Refractive Index:n20/D 1.418 
  • Boiling Point:132-134 ºC 
  • Flash Point:99 ºF 
  • PSA:26.30000 
  • Density:1.152 
  • LogP:0.78670 
  • XLogP3:1.1
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:2
  • Rotatable Bond Count:2
  • Exact Mass:122.0134572
  • Heavy Atom Count:7
  • Complexity:72.1
Purity/Quality:

≥99%, *data from raw suppliers

Methyl (R)-(+)-2-Chloropropionate *data from reagent suppliers

Safty Information:
  • Pictogram(s):  
  • Hazard Codes:Xi 
  • Statements: 10-36/37/38 
  • Safety Statements: 26-36 
MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:
  • Canonical SMILES:CC(C(=O)OC)Cl
  • Isomeric SMILES:C[C@H](C(=O)OC)Cl
  • Uses Chiral starting material
Technology Process of (R)-methyl 2-chloropropanoate

There total 11 articles about (R)-methyl 2-chloropropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With pyridine; thionyl chloride; at 20 ℃; for 0.0166667h;
Guidance literature:
With pyridine; thionyl chloride; In N,N-dimethyl-formamide; at 20 - 55 ℃; for 6h;
Guidance literature:
With aluminium trichloride; In dichloromethane; at 40 ℃; for 24h;
DOI:10.1016/S0040-4039(01)80743-7
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