platinum(2+) chloride - N-methylethane-1,2-diamine (1:2:1)

Base Information

• Chemical Name: platinum(2+) chloride - N-methylethane-1,2-diamine (1:2:1)
• CAS No.: 25956-83-6
• Molecular Formula: C₃H₁₀Cl₂N₂Pt
• Molecular Weight: 340.112
• Mol file: 25956-83-6.mol

Synonyms:Platinum,dichloro(N-methyl-1,2-ethanediamine-N,N')-, (SP-4-3)-; Platinum, dichloro(N-methylethylenediamine)-,(?à)- (8CI); 1,2-Ethanediamine,N-methyl-, platinum complex; Dichloro(N-methylethylenediamine)platinum

Chemical Property of platinum(2+) chloride - N-methylethane-1,2-diamine (1:2:1)

Chemical Property:

• Vapor Pressure: 19.4mmHg at 25°C
• Boiling Point: 115°Cat760mmHg
• Flash Point: 41.1°C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of platinum(2+) chloride - N-methylethane-1,2-diamine (1:2:1)

There total 6 articles about platinum(2+) chloride - N-methylethane-1,2-diamine (1:2:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

potassium tetrachloroplatinate(II) (10025-99-7) + N-methyl-ethane-1,2-diamine (109-81-9) → cis-dichloro(N-methylethylenediamine)platinum(II) (25956-83-6)

Guidance literature:

In water; mixing, stirring for 15-20 min; ppt. was filtered off, recrystd. from hot 0.1 M HCl; elem. anal.;

Reference yield:

cis-(N-methyl-ethylenediamine)diiodoplatinum(II) (110946-31-1) + potassium chloride → cis-dichloro(N-methylethylenediamine)platinum(II) (25956-83-6)

Guidance literature:

cis-(N-methyl-ethylenediamine)diiodoplatinum(II); With silver nitrate; In water; at 50 ℃; for 24h;

potassium chloride;

DOI:10.1039/c2dt32360e

Reference yield:

cis-(N-methyl-ethylenediamine)diiodoplatinum(II) (110946-31-1) + potassium chloride + water (7732-18-5) → cis-dichloro(N-methylethylenediamine)platinum(II) (25956-83-6)

Guidance literature:

With silver sulfate; In water; byproducts: AgI; Ag:Pt=1.28:0.65 molar ratio, Pt compd. added to a soln. of Ag salt, stirred overnight at 40°C in the dark, filtered, KCl (excess) added, stored for 24 h; ppt. centrifuged, washed (cold water, ethanol, diethyl ether), dried (vac.);

DOI:10.1016/j.ica.2008.02.004

upstream raw materials:

potassium tetrachloroplatinate(II)

N-methyl-ethane-1,2-diamine

ferrocene

platinum(IV)Cl₄(meen)

Refernces

• 1、 Milanesio, Marco,Monti, Elena,Gariboldi, Marzia Bruna,Gabano, Elisabetta,Ravera, Mauro,Osella, Domenico. "Trend in cytotoxic activity of a series of cis-[APtCl2] (A = ethylenediamine methylated at different positions) complexes". . p. 2803 - 2814. Retrieved 2009/02/03.
• 2、 Peloso, Arnaldo,Mohamud, Sacid Issa. "Atom-transfer and outer-sphere reductions of platinum(IV) complexes. A comparative kinetic investigation". . p. 349 - 354. Retrieved 2007/10/02.