N-ALLYLPHTHALIMIDE

Base Information

• Chemical Name: N-ALLYLPHTHALIMIDE
• CAS No.: 5428-09-1
• Molecular Formula: C11H9 N O2
• Molecular Weight: 187.198
• Hs Code.: 2925190090
• Mol file: 5428-09-1.mol

Synonyms:1H-Isoindole-1,3(2H)-dione,2-(2-propenyl)- (9CI); Phthalimide, N-allyl- (7CI,8CI);2-(2-Propen-1-yl)-1H-isoindol-1,3(2H)-dione; 2-Allylisoindoline-1,3-dione;Allylphthalimide; N-(2-Propenyl)phthalimide; N-Allylphthalimide; NSC 12801

Chemical Property of N-ALLYLPHTHALIMIDE

Chemical Property:

• Vapor Pressure: 0.00145mmHg at 25°C
• Melting Point: 68.0 to 72.0 °C
• Boiling Point: 296.2°Cat760mmHg
• PKA: -2.18±0.20(Predicted)
• Flash Point: 129°C
• PSA: 37.38000
• Density: 1.233g/cm³
• LogP: 1.40650
• Storage Temp.: 2-8°C

Purity/Quality:

97% ^*data from raw suppliers

N-Allylphthalimide >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of N-ALLYLPHTHALIMIDE

There total 5 articles about N-ALLYLPHTHALIMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

phthalic anhydride (85-44-9) + 1-amino-2-propene (107-11-9,30551-89-4) → 3-phthalimido-1-propene (5428-09-1)

Guidance literature:

In water; ethyl acetate; N,N-dimethyl-formamide;

Reference yield: 84.0%

N-propargylphthalimide (7223-50-9) → N-propylphthalimide (5323-50-2) + 3-phthalimido-1-propene (5428-09-1)

Guidance literature:

With hydrogen; In toluene; at 110 ℃; for 4h; under 760.051 Torr; Time; Schlenk technique;

DOI:10.1055/s-0037-1610318

Reference yield: 80.0%

carbon monoxide (201230-82-2) + 1-amino-2-propene (107-11-9,30551-89-4) + 2,3-dibromobenzene (583-53-9) → 3-phthalimido-1-propene (5428-09-1) + N-allyl-2-bromo-benzamide (88229-24-7)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; at 110 ℃; for 24h; under 15514.9 Torr; Ionic liquid; Autoclave;

DOI:10.1021/ol101714p

upstream raw materials:

phthalic anhydride

1-amino-2-propene

methanol

benzene

Downstream raw materials:

N-allyl-phthalamic acid

Dithiocarbonic acid S-[4-(4-bromo-phenyl)-1-(1,3-dioxo-1,3-dihydro-isoindol-2-ylmethyl)-4-oxo-butyl] ester O-ethyl ester

O-ethyl S-4-oxo-4-phenyl-1-phthalimidomethylbutyl dithiocarbonate

dithiocarbonic acid S-[1-(1,3-dioxo-1,3-dihydro-isoindol-2-ylmethyl)-4-(4-methoxy-phenyl)-4-oxo-butyl] ester O-ethyl ester