Lithium, [2-cyclohexyl-1-(trimethylstannyl)ethenyl]-, (Z)-

Base Information

• Chemical Name: Lithium, [2-cyclohexyl-1-(trimethylstannyl)ethenyl]-, (Z)-
• CAS No.: 97537-73-0
• Molecular Formula: C₁₁H₂₁LiSn
• Molecular Weight: 278.939

Synonyms:

Chemical Property of Lithium, [2-cyclohexyl-1-(trimethylstannyl)ethenyl]-, (Z)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Lithium, [2-cyclohexyl-1-(trimethylstannyl)ethenyl]-, (Z)-

There total 2 articles about Lithium, [2-cyclohexyl-1-(trimethylstannyl)ethenyl]-, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

C6H11CHC(Sn(CH3)3)2 (89029-46-9) + methyllithium (917-54-4) → C6H11CHC(Li)Sn(CH3)3 (97537-73-0,97537-96-7) + C6H11CHC(Li)Sn(CH3)3 (97537-73-0,97537-96-7)

Guidance literature:

In further solvent(s); byproducts: Me4Sn; a soln. of distannylalkene in Me2NCH2CH2NMe2 was added dropwise under Ar to a soln. of MeLi in the same solvent at -78°C in 1:1 molar ratio, mixt. was examined by (1)H NMR spectroscopy at room temp.; only Z-isomer was formed; vinyllithium was not obtained in pure form; (1)H NMR data at room temp.;

DOI:10.1016/0022-328X(87)85002-7

Reference yield: 69.0%

C6H11CHC(Sn(CH3)3)2 (89029-46-9) + methyllithium (917-54-4) → C6H11CHC(Li)Sn(CH3)3 (97537-73-0,97537-96-7) + C6H11CHC(Li)Sn(CH3)3 (97537-73-0,97537-96-7)

Guidance literature:

In further solvent(s); byproducts: Me4Sn; a soln. of distannylalkene in Me2NCH2CH2NMe2 was added dropwise under Ar to a soln. of MeLi in the same solvent at -78°C in 1:1 molar ratio, mixt. was examined by (1)H NMR spectroscopy at room temp.; only Z-isomer was formed; vinyllithium was not obtained in pure form; (1)H NMR data at room temp.;

DOI:10.1016/0022-328X(87)85002-7

Reference yield: 42.0%

chloro-trimethyl-silane (75-77-4) + C6H11CHC(Li)Sn(CH3)3 (97537-73-0,97537-96-7) + methyllithium (917-54-4) → C6H11CHC(Si(CH3)3)Sn(CH3)3 (97537-88-7,97537-89-8) + ((Z)-2-Cyclohexyl-1-trimethylstannanyl-vinyl)-trimethyl-silane

Guidance literature:

With water; In tetrahydrofuran; to soln. of MeLi at -78°C was slowly added soln. of Sn compd., after 2 h Me3SiCl was added, mixt. was allowed to warm up to room temp. and treated with water; solvent was removed and residue distd.; elem. anal.; mixt. of E/Z isomers 50/50;

DOI:10.1016/0022-328X(85)87105-9

upstream raw materials:

C₆H₁₁CHC(Sn(CH₃)3)2

methyllithium

Downstream raw materials:

C₆H₁₁HCC(CH₃)Sn(CH₃)3

C₆H₁₁HCC(CH₃)Sn(CH₃)3

C₆H₁₁CHC(Si(CH₃)3)Sn(CH₃)3

C₆H₁₁CHCD(Sn(CH₃)3)

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 97537-73-0 Lithium, [2-cyclohexyl-1-(trimethylstannyl)ethenyl]-, (Z)-

Send

Send

Metric Ton KG G Pound L ML

Send

Send