1,5-Hexanediol, dibenzoate

Base Information

• Chemical Name: 1,5-Hexanediol, dibenzoate
• CAS No.: 98936-67-5
• Molecular Formula: C20H22O4
• Molecular Weight: 326.392
• Mol file: 98936-67-5.mol

Synonyms:

Chemical Property of 1,5-Hexanediol, dibenzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,5-Hexanediol, dibenzoate

There total 6 articles about 1,5-Hexanediol, dibenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

hexane-1,5-diol (928-40-5) + vinyl benzoate (769-78-8,24991-32-0) → 1-benzoyloxy-5-hydroxyhexane (98936-68-6) + (S)-hexane-1,5-diyl dibenzoate (98936-67-5)

Guidance literature:

With 1,3-dichlorotetrabutyldistannoxane; at 50 ℃; for 40h;

DOI:10.1021/jo9800412

Reference yield:

2-Heptanol (52390-72-4,543-49-7) + benzoyl chloride (98-88-4) → (S)-hexane-1,5-diyl dibenzoate (98936-67-5)

Guidance literature:

With pyridine; In dichloromethane; at 20 - 25 ℃; for 2h; Inert atmosphere;

DOI:10.1016/j.tet.2019.130680

Reference yield:

hexane-1,5-diol (928-40-5) + 3-acyl-2-oxazolone(R=Ph) (60759-50-4) → 1-benzoyloxy-5-hydroxyhexane (98936-68-6) + (S)-hexane-1,5-diyl dibenzoate (98936-67-5)

Guidance literature:

zirconium acetylacetonate; In dichloromethane; at 25 ℃; for 68h; Yield given. Yields of byproduct given;

DOI:10.1016/S0040-4039(00)98356-4

upstream raw materials:

chloro-trimethyl-silane

hexane-1,5-diol

benzoyl chloride

3-acyl-2-oxazolone(R=Ph)