4-[(Benzyloxy)methyl]-1-methyl-2,6,7-trioxabicyclo[2.2.2]octane

Base Information

Chemical Name:4-[(Benzyloxy)methyl]-1-methyl-2,6,7-trioxabicyclo[2.2.2]octane
CAS No.:99231-99-9
Molecular Formula:C14H18O4
Molecular Weight:250.295
Hs Code.:
DSSTox Substance ID:DTXSID30564261
Wikidata:Q82448906

Synonyms:99231-99-9;SCHEMBL5575731;DTXSID30564261;4-[(Benzyloxy)methyl]-1-methyl-2,6,7-trioxabicyclo[2.2.2]octane

Suppliers and Price of 4-[(Benzyloxy)methyl]-1-methyl-2,6,7-trioxabicyclo[2.2.2]octane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 4-[(Benzyloxy)methyl]-1-methyl-2,6,7-trioxabicyclo[2.2.2]octane

Chemical Property:

XLogP3:1.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:250.12050905
Heavy Atom Count:18
Complexity:261

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC12OCC(CO1)(CO2)COCC3=CC=CC=C3

Technology Process of 4-[(Benzyloxy)methyl]-1-methyl-2,6,7-trioxabicyclo[2.2.2]octane

There total 4 articles about 4-[(Benzyloxy)methyl]-1-methyl-2,6,7-trioxabicyclo[2.2.2]octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 100-39-0
benzyl bromide

: 19309-39-8
1-methyl-4-(hydroxymethyl)-2,6,7-trioxabicyclo-[2.2.2]-octane

: 99231-99-9
4-<(benzyloxy)methyl>-1-methyl-2,6,7-trioxabicyclo<2.2.2>octane

Guidance literature:: With potassium hydroxide; In dimethyl sulfoxide; for 1h; Inert atmosphere;
DOI:10.1002/chem.201700783

Reference yield:

: 115-77-5
Pentaerythritol

: 99231-99-9
4-<(benzyloxy)methyl>-1-methyl-2,6,7-trioxabicyclo<2.2.2>octane

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / p-toluenesulfonic acid monohydrate / toluene / 80 - 125 °C

2: KOH / dimethylsulfoxide / 2 h / 20 °C

With potassium hydroxide; toluene-4-sulfonic acid; In dimethyl sulfoxide; toluene;
DOI:10.1016/j.tet.2007.03.004