2-(BROMOMETHYL)BENZYLTRIPHENYLPHOSPHONIUM BROMIDE

Base Information

• Chemical Name: 2-(BROMOMETHYL)BENZYLTRIPHENYLPHOSPHONIUM BROMIDE
• CAS No.: 67219-44-7
• Molecular Formula: C26H22BrP
• Molecular Weight: 526.25
• Mol file: 67219-44-7.mol

Synonyms:-triphenyl-phosphonium;

Chemical Property of 2-(BROMOMETHYL)BENZYLTRIPHENYLPHOSPHONIUM BROMIDE

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 13.59000
• Density: g/cm³
• LogP: 3.07960

Purity/Quality:

99% ^*data from raw suppliers

2-(BROMOMETHYL)BENZYLTRIPHENYLPHOSPHONIUM BROMIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-(BROMOMETHYL)BENZYLTRIPHENYLPHOSPHONIUM BROMIDE

There total 1 articles about 2-(BROMOMETHYL)BENZYLTRIPHENYLPHOSPHONIUM BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

triphenylphosphine (603-35-0) + α,α'-dibromo-o-xylene (91-13-4) → (2-(bromomethyl)benzyl)triphenyl-1-phosphonium bromide (67219-44-7)

Guidance literature:

In benzene; for 8h; Heating;

DOI:10.1021/jo9917994

Reference yield: 98.0%

sodium benzoate (532-32-1) + (2-(bromomethyl)benzyl)triphenyl-1-phosphonium bromide (67219-44-7) → [(o-benzoyloxymethyl)phenylmethyl]triphenylphosphonium bromide

Guidance literature:

In water; acetone; Ambient temperature;

DOI:10.1021/jo961496z

Reference yield: 96.0%

sodium anisate (536-45-8) + (2-(bromomethyl)benzyl)triphenyl-1-phosphonium bromide (67219-44-7) → [2-(4-Methoxy-benzoyloxymethyl)-benzyl]-triphenyl-phosphonium; bromide

Guidance literature:

In water; acetone; Ambient temperature;

DOI:10.1021/jo961496z

upstream raw materials:

triphenylphosphine

α,α'-dibromo-o-xylene

Downstream raw materials:

2-(2-Formylphenyloxymethyl)-benzyl-triphenylphosphonium bromide

ethyl 2-tert-butoxycarbonyl-1,2-dihydroisoquinoline-3-carboxylate

3-(4-methoxyphenyl)-1H-isochromene

3-phenyl-1H-isochromene

Refernces

• 1、 Naghipour, Ali,Ghorbani-Choghamarani, Arash,Heidarizadi, Fateme,Notash, Behrouz. "Synthesis, characterization and structural study of a phosphonium salt containing the [Pd2Br6]2- ion and its application as a novel, efficient and renewable heterogeneous catalyst for amination of aryl halides and the Stille cross-coupling reaction". . p. 18 - 26. Retrieved 2016/01/12.
• 2、 Czombos, Jozsef,Aelterman, Wim,Tkachev, Alexey,Martins, Jose C.,Tourwe, Dirk,Peter, Antal,Toeth, Geza,Fueloep, Ferenc,De Kimpe, Norbert. "Convenient Synthesis of 3,4-methano-1,2,3,4-tetrahydroisoquinoline-3-carboxylic Acid and Its Derivatives as Doubly Constrained Nonproteinogenic Amino Acid Derivatives". . p. 5469 - 5475. Retrieved 2007/10/03.