Aliphatics

Base Information

• Chemical Name: Aliphatics
• CAS No.: 37839-01-3
• Molecular Formula: C₂H₉N₄S*I
• Molecular Weight: 248.091
• Hs Code.: 2930909090
• Mol file: 37839-01-3.mol

Synonyms:methyl hydrazinecarbohydrazonothioate hydroiodide;

Chemical Property of Aliphatics

Chemical Property:

• Vapor Pressure: 0.0131mmHg at 25°C
• Melting Point: 145 °C (decomp)
• Boiling Point: 259.2°C at 760 mmHg
• Flash Point: 110.6°C
• PSA: 101.73000
• LogP: 1.83210

Purity/Quality:

99% ^*data from raw suppliers

MethylHydrazine-1-carbohydrazonothioateHydroiodide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Aliphatics

There total 1 articles about Aliphatics which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

Thiocarbohydrazide (2231-57-4) + methyl iodide (74-88-4) → 1H(+)-S-methylisothiocarbonohydrazidium iodide (37839-01-3,67708-03-6)

Guidance literature:

In ethanol; at 80 ℃; for 3h;

DOI:10.1002/anie.202005569

Reference yield:

1H(+)-S-methylisothiocarbonohydrazidium iodide (37839-01-3,67708-03-6) + pyridine-4-methylimine acid ethyl ester (41050-96-8) → 3-methylsulfanyl-6-(4-pyridyl)-1,2-dihydro-1,2,4,5-tetrazine

Guidance literature:

With pyridine; In water; at 0 - 20 ℃; for 24h;

Reference yield:

C14H18O4 + 1H(+)-S-methylisothiocarbonohydrazidium iodide (37839-01-3,67708-03-6) → C11H14N4OS

Guidance literature:

With pyridine; In N,N-dimethyl-formamide; at 80 ℃; Reagent/catalyst; Temperature; Inert atmosphere;

DOI:10.1002/anie.202005569

upstream raw materials:

Thiocarbohydrazide

methyl iodide

Downstream raw materials:

4-(5-hydrazino-[1,3,4]thiadiazol-2-yl)-N,N-dimethyl-aniline

NCHC(CH₃)N₂CS(CH₃)N₂CHC(CH₃)N₂CS(CH₃)NNi

NC(CH₃)CHN₂CS(CH₃)N₂C(CH₃)CHN₂CS(CH₃)NNi

NC(CH₃)CHN₂CS(CH₃)N₂CHC(CH₃)N₂CS(CH₃)NNi

Refernces

• 1、 -. "HERBICIDAL PYRIDINIUM COMPOUNDS". Page/Page column 83. . Retrieved 2020/08/22.