tert-Butyl 2-(4-methoxybenzyl)hydrazinecarboxylate

Base Information

Chemical Name:tert-Butyl 2-(4-methoxybenzyl)hydrazinecarboxylate
CAS No.:150767-02-5
Molecular Formula:C13H20N2O3
Molecular Weight:252.313
Hs Code.:2928000090
DSSTox Substance ID:DTXSID001168299
Nikkaji Number:J3.063.660K
Mol file:150767-02-5.mol

Synonyms:150767-02-5;Tert-butyl N-[(4-methoxyphenyl)methylamino]carbamate;Tert-butyl N-[(4-;tert-Butyl 2-(4-methoxybenzyl)hydrazinecarboxylate;Methoxyphenyl)MethylaMino]carbaMate;SCHEMBL2493016;LAAOJPYAGIBKBK-UHFFFAOYSA-N;DTXSID001168299;N'-(4-Methoxybenzyl)carbazic acid tert-butyl ester;1,1-Dimethylethyl 2-[(4-methoxyphenyl)methyl]hydrazinecarboxylate

Suppliers and Price of tert-Butyl 2-(4-methoxybenzyl)hydrazinecarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
TERT-BUTYL-N-[(4-METHOXYPHENYL)METHYLAMINO]CARBAMATE 95.00%
5MG
$ 501.27

Total 9 raw suppliers

Chemical Property of tert-Butyl 2-(4-methoxybenzyl)hydrazinecarboxylate

Chemical Property:

PKA:10.45±0.43(Predicted)
PSA：54.29000
Density:1.080±0.06 g/cm3(Predicted)
LogP:2.77550
XLogP3:2.2
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:6
Exact Mass:252.14739250
Heavy Atom Count:18
Complexity:256

Purity/Quality:

99%, ^*data from raw suppliers

TERT-BUTYL-N-[(4-METHOXYPHENYL)METHYLAMINO]CARBAMATE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)OC(=O)NNCC1=CC=C(C=C1)OC

Technology Process of tert-Butyl 2-(4-methoxybenzyl)hydrazinecarboxylate

There total 10 articles about tert-Butyl 2-(4-methoxybenzyl)hydrazinecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: tert-butyl (E)-2-(4-methoxybenzylidene)hydrazine-1-carboxylate

: 150767-02-5
N-1-(tert-butoxycarbonyl)-N-2-<(4-methoxyphenyl)methyl>hydrazine

Guidance literature:: With hydrogen; palladium 10% on activated carbon; In tetrahydrofuran; water; ethyl acetate; at 20 ℃; under 2585.81 Torr; Sealed tube;

Reference yield: 70.0%

: 150767-00-3
N-t-butoxycarbonyl-N'-4-methoxybenzaldehyde hydrazone

: 150767-02-5
N-1-(tert-butoxycarbonyl)-N-2-<(4-methoxyphenyl)methyl>hydrazine

Guidance literature:: With palladium 10% on activated carbon; sodium formate; In ethanol; water;
DOI:10.3390/molecules20059229

Reference yield:

: 870-46-2
t-butoxycarbonylhydrazine

: 150767-02-5
N-1-(tert-butoxycarbonyl)-N-2-<(4-methoxyphenyl)methyl>hydrazine

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / 20 °C

2: 30 percent / NaBH₃CN; p-toluenesulfonic acid; bromocresol green / tetrahydrofuran / 5 h

With bromocresol green; sodium cyanoborohydride; toluene-4-sulfonic acid; In tetrahydrofuran;