1-((1R,3S,6R)-6-methyl-7-oxabicyclo[4.1.0]heptan-3-yl) ethanone

Base Information

• Chemical Name: 1-((1R,3S,6R)-6-methyl-7-oxabicyclo[4.1.0]heptan-3-yl) ethanone
• CAS No.: 111613-37-7
• Molecular Formula: C9H14O2
• Molecular Weight: 154.209
• Mol file: 111613-37-7.mol

Synonyms:1-((1R,3S,6R)-6-methyl-7-oxabicyclo[4.1.0]heptan-3-yl) ethanone

Chemical Property of 1-((1R,3S,6R)-6-methyl-7-oxabicyclo[4.1.0]heptan-3-yl) ethanone

Chemical Property:

• Boiling Point: 220.1±23.0 °C(Predicted)
• PSA: 29.60000
• Density: 1.084±0.06 g/cm3(Predicted)
• LogP: 1.53300

Purity/Quality:

98%min ^*data from raw suppliers

1-((1R,3S,6R)-6-METHYL-7-OXABICYCLO[4.1.0]HEPTAN-3-YL)ETHANONE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
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MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-((1R,3S,6R)-6-methyl-7-oxabicyclo[4.1.0]heptan-3-yl) ethanone

There total 3 articles about 1-((1R,3S,6R)-6-methyl-7-oxabicyclo[4.1.0]heptan-3-yl) ethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

(-)-limonene oxide (203719-53-3) → (1S,2R,4S)-4-Acetyl-1,2-epoxy-1-methylcyclohexane (111613-38-8,1932365-85-9) + (1R,2S,4S)-4-Acetyl-1,2-epoxy-1-methylcyclohexane (111613-37-7,1932365-85-9)

Guidance literature:

With potassium permanganate; dibenzo-18-crown-6; 18-crown-6 ether; In dichloromethane; at 20 ℃; for 10h;

DOI:10.1055/s-2000-6253

Reference yield:

(-)-(S)-limonene (5989-54-8,555-08-8,8022-90-0,9003-73-0,95327-98-3) + dimethyl amine (124-40-3) → (1R,2S,4S)-4-Acetyl-1,2-epoxy-1-methylcyclohexane (111613-37-7,1932365-85-9)

Guidance literature:

Multistep reaction;

DOI:10.1039/c39870000414

Reference yield:

→ 1-((1R,6S)-6-Methyl-7-oxa-bicyclo[4.1.0]hept-3-yl)-ethanone (57072-60-3,57129-05-2,111613-37-7,111613-38-8,143344-49-4,143344-50-7,148154-91-0,149251-77-4,149251-80-9,1932365-85-9)

Guidance literature:

1,2-Epoximenthen (5a), Ozon, Triphenylphosphin;

DOI:10.1002/hlca.19750580418

upstream raw materials:

(-)-(S)-limonene

dimethyl amine

(-)-limonene oxide

Downstream raw materials:

(Z)-(1R,2S,4S)-4-(1',5'-Dimethylhexa-1',4'-dienyl)-1,2-epoxy-1-methylcyclohexane

erythro-(1R,2S,4S)-4-(1',5'-Dimethyl-2'-diphenylphosphinoyl-1'-hydroxyhex-4'-enyl)-1,2-epoxy-1-methylcyclohexane

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