2,2'-Bipyridine-6-carboxylic acid

Base Information

Chemical Name:2,2'-Bipyridine-6-carboxylic acid
CAS No.:4392-87-4
Molecular Formula:C11H8N2O2
Molecular Weight:200.197
Hs Code.:2933399090
DSSTox Substance ID:DTXSID80452568
Nikkaji Number:J825.035I
Wikidata:Q82273283
Mol file:4392-87-4.mol

Synonyms:4392-87-4;2,2'-Bipyridine-6-carboxylic acid;[2,2'-Bipyridine]-6-carboxylic acid;6-pyridin-2-ylpyridine-2-carboxylic Acid;2,2-bipyridine-6-carboxylic acid;[2,2'-Bipyridine]-6-carboxylic acid hydrochloride;SCHEMBL4811257;YSCH0067;2,2-bipyridine-6-carboxylicacid;DTXSID80452568;AMY28740;MFCD11100046;[2,2'-Bipyridine]-6-carboxylicacid;2,2''-bipyridine-6-carboxylic acid;AKOS026675804;CS-W004555;TS-02832;FT-0751405;E10011;J-400155

Suppliers and Price of 2,2'-Bipyridine-6-carboxylic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Matrix Scientific
2,2'-Bipyridine-6-carboxylic acid 97%
1g
$ 820.00

Chemenu
[2,2''-Bipyridine]-6-carboxylicacid 97%
1g
$ 577.00

Biosynth Carbosynth
2,2'-Bipyridine-6-carboxylic acid
100 mg
$ 110.00

Biosynth Carbosynth
2,2'-Bipyridine-6-carboxylic acid
50 mg
$ 70.00

Biosynth Carbosynth
2,2'-Bipyridine-6-carboxylic acid
25 mg
$ 45.00

Biosynth Carbosynth
2,2'-Bipyridine-6-carboxylic acid
250 mg
$ 220.00

Biosynth Carbosynth
2,2'-Bipyridine-6-carboxylic acid
500 mg
$ 350.00

Atlantic Research Chemicals
2,2''-Bipyridine-6-carboxylicacid 95%
1gm:
$ 374.66

Ambeed
[2,2'-Bipyridine]-6-carboxylicacid 97%
250mg
$ 185.00

Ambeed
[2,2'-Bipyridine]-6-carboxylicacid 97%
100mg
$ 115.00

Total 15 raw suppliers

Chemical Property of 2,2'-Bipyridine-6-carboxylic acid

Chemical Property:

Melting Point:210-220 °C (decomp)
Boiling Point:427.7±35.0 °C(Predicted)
PKA:2.93±0.10(Predicted)
Flash Point:212.491oC
PSA：63.08000
Density:1.302±0.06 g/cm3(Predicted)
LogP:1.84180
Storage Temp.:2-8°C
XLogP3:1.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:200.058577502
Heavy Atom Count:15
Complexity:233

Purity/Quality:

99%, ^*data from raw suppliers

2,2'-Bipyridine-6-carboxylic acid 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=NC(=C1)C2=NC(=CC=C2)C(=O)O
Uses 2,2'-Bipyridine-6-carboxylic Acid is a useful research chemical compound. Developed in the Engle lab, this 2,2′-bipyridylamide (PPA) is a pincer-like, removable tridentate directing group that stabilizes 6-membered palladacycles for olefin functionalization. Together with similar ligand PAQ (901250), researchers demonstrated regioselective remote hydrocarbofunctionalization of alkene-containing substrate classes (e.g. 4-pentenoic acids, allylic alcohols, homoallyl amines, bis-homoallylamines) using Pd(II) catalysis.

Technology Process of 2,2'-Bipyridine-6-carboxylic acid

There total 1 articles about 2,2'-Bipyridine-6-carboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 4392-85-2
2,2'-bipyridyl-6-carbonitrile

: 207610-55-7
[2,2’-bipyridine]-6-carboxamide

: 4392-87-4
2,2′-bipyridine-6-monocarboxylic acid

Guidance literature:: With sodium hydroxide; In methanol; water; for 11h; Heating;
DOI:10.3891/acta.chem.scand.52-0077

Reference yield: 52.0%

: 112245-13-3
(S)-tert-leucinol

: 106-49-0,12221-03-3
p-toluidine

: 4392-87-4
2,2′-bipyridine-6-monocarboxylic acid

: (S)-6-(4-(tert-butyl)-1-(p-tolyl)-4,5-dihydro-1H-imidazol-2-yl)-2,2′-bipyridine

Guidance literature:: 2,2′-bipyridine-6-monocarboxylic acid; With thionyl chloride; for 8h; Reflux;

(S)-tert-leucinol; With triethylamine; In dichloromethane; at 20 ℃; Cooling with ice;

p-toluidine; Further stages;

Reference yield: 52.0%

: 20859-02-3
L-tert-Leucine

: 106-49-0,12221-03-3
p-toluidine

: 4392-87-4
2,2′-bipyridine-6-monocarboxylic acid

: (S)-6-(4-(tert-butyl)-1-(p-tolyl)-4,5-dihydro-1H-imidazol-2-yl)-2,2′-bipyridine

Guidance literature:: 2,2′-bipyridine-6-monocarboxylic acid; With thionyl chloride; for 8h; Reflux;

L-tert-Leucine; With triethylamine; In dichloromethane; at 20 ℃; Cooling with ice;

p-toluidine; With triethylamine; In dichloromethane; at 20 ℃; Cooling with ice;