[2,2'-Bipyridine]-6-carbonitrile

Base Information

Chemical Name:[2,2'-Bipyridine]-6-carbonitrile
CAS No.:4392-85-2
Molecular Formula:C11H7N3
Molecular Weight:181.197
Hs Code.:2933399090
European Community (EC) Number:807-956-5
DSSTox Substance ID:DTXSID40454982
Nikkaji Number:J1.223.867C
Mol file:4392-85-2.mol

Synonyms:4392-85-2;[2,2'-Bipyridine]-6-carbonitrile;6-CYANO-2,2'-BIPYRIDINE;2,2'-bipyridine-6-carbonitrile;6-pyridin-2-ylpyridine-2-carbonitrile;AKOS BBS-00002967;6-Cyano-2,2'-bipyridyl;6-(PYRIDIN-2-YL)PYRIDINE-2-CARBONITRILE;6-cyano-bipyridine;6-Cyano-2,2-bipyridin;YSWG793;SCHEMBL994386;AMY7442;DTXSID40454982;QLZHLNAALBJVOE-UHFFFAOYSA-N;BCP21146;MFCD07364147;STL227763;AKOS000271617;MB04317;AS-46656;B4557;CS-0086393;E10012;EN300-722348;A872616;J-400789;Z1198171850

Suppliers and Price of [2,2'-Bipyridine]-6-carbonitrile

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2,2''-Bipyridine-6-carbonitrile
2.5mg
$ 45.00

TCI Chemical
2,2'-Bipyridine-6-carbonitrile >98.0%(GC)
200mg
$ 181.00

TCI Chemical
2,2'-Bipyridine-6-carbonitrile >98.0%(GC)
1g
$ 629.00

Crysdot
[2,2'-Bipyridine]-6-carbonitrile 95+%
1g
$ 507.00

Chem-Impex
2,2'-Bipyridine-6-carbonitrile,98%(GC) 98%(GC)
1G
$ 725.76

Chem-Impex
2,2'-Bipyridine-6-carbonitrile,≥98%(GC) ≥98%(GC)
200MG
$ 196.85

Chemenu
[2,2''-Bipyridine]-6-carbonitrile 95%
1g
$ 479.00

American Custom Chemicals Corporation
6-CYANO-2,2'-BIPYRIDINE 95.00%
5MG
$ 497.50

Alichem
[2,2'-Bipyridine]-6-carbonitrile
1g
$ 504.00

Alichem
[2,2'-Bipyridine]-6-carbonitrile
250mg
$ 225.50

Total 29 raw suppliers

Chemical Property of [2,2'-Bipyridine]-6-carbonitrile

Chemical Property:

Melting Point:130-131℃
Boiling Point:362.0±32.0℃ (760 Torr)
PKA:3.45±0.22(Predicted)
Flash Point:124.7±10.3℃
PSA：49.57000
Density:1.24±0.1 g/cm3 (20 ºC 760 Torr)
LogP:2.01528
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
XLogP3:1.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:181.063997236
Heavy Atom Count:14
Complexity:230

Purity/Quality:

99% ^*data from raw suppliers

2,2''-Bipyridine-6-carbonitrile ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=NC(=C1)C2=CC=CC(=N2)C#N

Technology Process of [2,2'-Bipyridine]-6-carbonitrile

There total 2 articles about [2,2'-Bipyridine]-6-carbonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 122918-25-6
6-bromopyridin-2-carbonitrile

: 17997-47-6
2-tri-n-butylstannylpyridine

: 4392-85-2
2,2'-bipyridyl-6-carbonitrile

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In 1,4-dioxane; at 180 ℃; for 0.25h; Microwave irradiation;
DOI:10.1016/j.tetlet.2015.01.182

Reference yield: 43.0%

: 366-18-7
[2,2]bipyridinyl

: 7677-24-9
trimethylsilyl cyanide

: 4392-85-2
2,2'-bipyridyl-6-carbonitrile

: 1613-71-4
[2,2'-bipyridine]-4-carbonitrile

Guidance literature:: [2,2]bipyridinyl; With trifluoromethylsulfonic anhydride; In chloroform; at 20 ℃; for 1h; Inert atmosphere; Sealed tube;

trimethylsilyl cyanide; In chloroform; at 60 ℃; for 3h; Inert atmosphere; Sealed tube;

With 4-methyl-morpholine; In chloroform; at 60 ℃; for 17h; Overall yield = 57 %; Inert atmosphere; Sealed tube;
DOI:10.1002/chem.201703931

Reference yield: 91.0%

: 4392-85-2
2,2'-bipyridyl-6-carbonitrile

: 29841-69-8
(S,S)-1,2-diphenyl-1,2-diaminoethane

: 98-59-9
p-toluenesulfonyl chloride

: 6-((4S,5S)-4,5-diphenyl-1-tosyl-4,5-dihydro-1H-imidazol-2-yl)-2,2′-bipyridine

Guidance literature:: 2,2'-bipyridyl-6-carbonitrile; With sodium methylate; In methanol; for 0.5h; Reflux;

(S,S)-1,2-diphenyl-1,2-diaminoethane; In dichloromethane; Reflux;

p-toluenesulfonyl chloride; With dmap; In dichloromethane; at 0 - 20 ℃; for 4h;