2-(3-Bromophenyl)-4,6-diphenyl-1,3,5-triazine

Base Information

• Chemical Name: 2-(3-Bromophenyl)-4,6-diphenyl-1,3,5-triazine
• CAS No.: 864377-31-1
• Molecular Formula: C21H14BrN3
• Molecular Weight: 388.266
• Hs Code.: 29339900
• Mol file: 864377-31-1.mol

Synonyms:2-(4-Bromophenyl)-4,6-diphenyl-1,3,5-triazine;

Chemical Property of 2-(3-Bromophenyl)-4,6-diphenyl-1,3,5-triazine

Chemical Property:

• Melting Point: 174.0 to 178.0 °C
• Boiling Point: 573.9 °C at 760 mmHg
• PKA: 0.65±0.10(Predicted)
• Flash Point: 300.9 °C
• PSA: 38.67000
• Density: 1.381 g/cm³
• LogP: 5.63510
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

99%+ ^*data from raw suppliers

2-(3-Bromophenyl)-4,6-diphenyl-1,3,5-triazine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 2-(3-Bromophenyl)-4,6-diphenyl-1,3,5-triazine is a useful research chemical.

Technology Process of 2-(3-Bromophenyl)-4,6-diphenyl-1,3,5-triazine

There total 18 articles about 2-(3-Bromophenyl)-4,6-diphenyl-1,3,5-triazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2-chloro-4,6-diphenyl-1,3,5-triazine (3842-55-5) + (3-bromophenyl)boronic acid (89598-96-9) → 2-(3-bromophenyl)-4,6-diphenyl-[1,3,5]triazine (864377-31-1)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In tetrahydrofuran; water; at 80 ℃; for 12h; Inert atmosphere;

Reference yield: 90.0%

(3-Bromophenyl)methanol (15852-73-0) + benzamidin (618-39-3) → 2-(3-bromophenyl)-4,6-diphenyl-[1,3,5]triazine (864377-31-1)

Guidance literature:

With oxygen; In toluene; at 110 ℃; for 20h; Schlenk technique;

DOI:10.1016/j.catcom.2019.05.005

Reference yield: 90.0%

benzamidine monohydrochloride (1670-14-0) + 3-bromobenzyl chloride (932-77-4) → 2-(3-bromophenyl)-4,6-diphenyl-[1,3,5]triazine (864377-31-1)

Guidance literature:

With sodium carbonate; sulfur; In dimethyl sulfoxide; at 130 ℃; for 24h;

upstream raw materials:

m-bromobenzoic aldehyde

N-(3-bromobenzylidene)-phenyl-amine

benzamidine monohydrochloride

3-bromobenzoyl chloride

Downstream raw materials:

9-[3-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl]-9'-phenyl-2,3'-bi-9H-carbazole

C₅₁H₃₃N₅

2-(3'-chloro-[1,1'-biphenyl]-3-yl)-4,6-diphenyl-1,3,5-triazine

Refernces

• 1、 -. "Electron transport material, preparation method thereof and organic light-emitting device". Paragraph 0067-0071; 0080-0084. . Retrieved 2021/04/14.
• 2、 -. "Heterocyclic com pounds and organic light-emitting diode including the same". Paragraph 0306-0311. . Retrieved 2021/02/02.