Bis(2-phenylquinoline)(acetylacetonate)iridium(III)

Base Information

• Chemical Name: Bis(2-phenylquinoline)(acetylacetonate)iridium(III)
• CAS No.: 1173886-71-9
• Molecular Formula: C35H27IrN2O2
• Molecular Weight: 699.82
• Mol file: 1173886-71-9.mol

Synonyms:Bis(2-phenylquinoline)(acetylacetonate)iridium(III);Ir(2-phq)2(acac) , Bis(2-phenylquinoline-C2,N')(acetylaceton

Chemical Property of Bis(2-phenylquinoline)(acetylacetonate)iridium(III)

Chemical Property:

• PSA: 41.90000
• LogP: 6.26690

Purity/Quality:

98% ^*data from raw suppliers

BIS(2-PHENYLQUINOLINE)(ACETYLACETONATE)IRIDIUM(III) 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bis(2-phenylquinoline)(acetylacetonate)iridium(III)

There total 8 articles about Bis(2-phenylquinoline)(acetylacetonate)iridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

tetrakis(2-phenylquinoline-C2,N')(μ-dichloro)diiridium(III) + acetylacetone (123-54-6,81235-32-7) → bis(2-phenylquinoline)(acetylacetonate)iridium(III) (337526-95-1,1173886-71-9)

Guidance literature:

With sodum carbonate; In further solvent(s); ((pq)2IrCl)2, 2,4-pentanedione, and Na2CO3 were refluxed under inert gasatm. in 2-ethoxyethanol for 12-15 h; mixt. was cooled to room temp., ppt. was filtered off. washed with water, Et2O, and hexane, chromy. on silica using CH2Cl2 as eluent; elem. anal.;

DOI:10.1021/ic0008969

Reference yield: 85.0%

pq2Ir(μ-Cl)2Irpq2 (632327-37-8,337526-84-8) + acetylacetone (123-54-6,81235-32-7) → bis(2-phenylquinoline)(acetylacetonate)iridium(III) (337526-95-1,1173886-71-9)

Guidance literature:

With potassium carbonate; In ethanol; water; for 48h; Heating / reflux;

Reference yield: 70.0%

[iridium(III)(μ-chloro)(2-phenylpyridine)2]2 + 2-Phenylquinoline (612-96-4) → bis(2-phenylquinoline)(acetylacetonate)iridium(III) (337526-95-1,1173886-71-9)

Guidance literature:

In not given; dimer refluxed with 2,4-pentandione;

DOI:10.1016/j.jpcs.2007.10.126

upstream raw materials:

pq2Ir(μ-Cl)2Irpq2

acetylacetone

2-Phenylquinoline

2-phenylpyridine

Downstream raw materials:

Ir(2-phenylquinoline)2(4-methyl-2,3-diphenylquinoline)

Refernces

• 1、 Zhao, Qiang,Jiang, Chang-Yun,Shi, Mei,Li, Fu-You,Yi, Tao,Cao, Yong,Huang, Chun-Hui. "Synthesis and photophysical, electrochemical, and electrophosphorescent properties of a series of iridium(III) complexes based on quinoline derivatives and different β-diketonate ligands". . p. 3631 - 3638. Retrieved 2006.
• 2、 Ahn, So Youn,Ko, Myung Joo,Ha, Yunkyoung. "The heteroleptic complexes containing 2,3-diphenylquinoline derivatives as phosphorescent materials". . p. 1320 - 1324. Retrieved 2009/01/31.