CID 11809239

Base Information

Chemical Name:CID 11809239
CAS No.:40661-45-8
Molecular Formula:C14H20O8
Molecular Weight:316.308
Hs Code.:
Nikkaji Number:J17.451C
Wikidata:Q104375849

Synonyms:cornoside

Suppliers and Price of CID 11809239

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 16 raw suppliers

Chemical Property of CID 11809239

Chemical Property:

Vapor Pressure:5.29E-17mmHg at 25°C
Boiling Point:602°Cat760mmHg
PKA:11.83±0.20(Predicted)
Flash Point:226.3°C
PSA：136.68000
Density:1.51g/cm³
LogP:-2.38080
XLogP3:-2.1
Hydrogen Bond Donor Count:5
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:5
Exact Mass:316.11581759
Heavy Atom Count:22
Complexity:444

Purity/Quality:: ≥98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC(C=CC1=O)(CCOC2C(C(C(C(O2)CO)O)O)O)O
Isomeric SMILES:C1=CC(C=CC1=O)(CCO[C@H]2[C@@H]([C@H]([C@@H]([C@H](O2)CO)O)O)O)O

Technology Process of CID 11809239

There total 11 articles about CID 11809239 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.1%

: 40593-03-1
Acetic acid (2R,3R,4S,5R,6R)-3,5-diacetoxy-2-acetoxymethyl-6-[2-(1-hydroxy-4-oxo-cyclohexa-2,5-dienyl)-ethoxy]-tetrahydro-pyran-4-yl ester

: 40661-45-8
cornoside

Guidance literature:: With sodium methylate; In methanol;
DOI:10.1248/cpb.46.581

Reference yield:

: 501-94-0
p-hydroxyphenethyl alcohol

: 40661-45-8
cornoside

Guidance literature:: Multi-step reaction with 4 steps

1: 73 percent / 1N aq. NaOH / tetrahydrofuran / 1 h / Ambient temperature

2: 1.) Ag₂CO₃, Drierite, 2.) I₂ / 1.) Et₂O, RT, 10 min, 2.) Et₂O, RT, 14 h

3: 97.7 percent / NaOMe / methanol / 1 h / Ambient temperature

4: 1.) O₂, 2.) Me₂S / 1.) MeOH, 20 deg C, irrad., 3 h, 2.) MeOH, 4 h

With calcium sulfate; sodium hydroxide; dimethylsulfide; iodine; oxygen; sodium methylate; silver carbonate; In tetrahydrofuran; methanol;
DOI:10.1248/cpb.46.581

Reference yield:

: 28251-63-0
tetraacetyl salidroside

: 40661-45-8
cornoside

Guidance literature:: Multi-step reaction with 2 steps

1: 11.5 percent / aq. thallium triperchlorate / CH₂Cl₂ / 0.25 h

2: 61.1 percent / NaOMe / methanol

With thallium(III) perchlorate; sodium methylate; In methanol; dichloromethane;
DOI:10.1248/cpb.46.581