Cobaltous formate

Base Information

• Chemical Name: Cobaltous formate
• CAS No.: 544-18-3
• Molecular Formula: 2CHO₂*Co
• Molecular Weight: 149.029
• European Community (EC) Number: 208-864-2
• UN Number: 3077
• UNII: 3ADO6Y1TNZ
• DSSTox Substance ID: DTXSID1060267
• Nikkaji Number: J43.243A
• Wikipedia: Cobalt(II)_formate
• Wikidata: Q1104467
• Mol file: 544-18-3.mol

Synonyms:aluminum formate;ammonium formate;ammonium tetraformate;calcium formate;chromic formate;cobalt(II) formate dihydrate;cobaltous formate;cupric formate;formate;formic acid;formic acid, 14C-labeled;formic acid, aluminum salt;formic acid, ammonium (2:1) salt;formic acid, ammonium (4:1) salt;formic acid, ammonium salt;formic acid, cadmium salt;formic acid, calcium salt;formic acid, cesium salt;formic acid, cobalt (+2) salt;formic acid, copper (+2) salt;formic acid, copper salt;formic acid, copper, ammonium salt;formic acid, copper, nickel salt;formic acid, cromium (+3) salt;formic acid, cromium (+3), sodium (4:1:1) salt;formic acid, lead (+2) salt;formic acid, lead salt;formic acid, lithium salt;formic acid, magnesium salt;formic acid, nickel (+2) salt;formic acid, nickel salt;formic acid, potassium salt;formic acid, rubidium salt;formic acid, sodium salt;formic acid, sodium salt, 13C-labeled;formic acid, sodium salt, 14C-labeled;formic acid, strontium salt;formic acid, thallium (+1) salt;formic acid, zinc salt;lead formate;lithium formate;magnesium formate;methanoic acid;nickel formate;nickel formate dihydrate;potassium formate;sodium formate;strontium formate;zinc formate

Chemical Property of Cobaltous formate

Chemical Property:

• Vapor Pressure: 36.5mmHg at 25°C
• Melting Point: 8.4oC
• Boiling Point: 100.6 ºC at 760 mmHg
• Flash Point: 29.9 ºC
• PSA: 52.60000
• Density: g/cm³
• LogP: 0.51920
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 148.928502
• Heavy Atom Count: 7
• Complexity: 7.5

Purity/Quality:

99% ^*data from raw suppliers

COBALTOUS FORMATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: C(=O)[O-].C(=O)[O-].[Co+2]

Technology Process of Cobaltous formate

There total 5 articles about Cobaltous formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

formic acid (64-18-6) + cobalt(II) nitrate hexahydrate → cobalt(II) formate (544-18-3,15731-88-1)

Guidance literature:

cobalt(II) nitrate hexahydrate; With sodium hydroxide; In water;

formic acid; In water;

DOI:10.1016/j.jallcom.2017.12.272

Reference yield:

formic acid (64-18-6) + cobalt(II) acetate (71-48-7,917-69-1,5931-89-5,55881-15-7,68931-68-0,68931-69-1,93029-27-7) → cobalt(II) formate (544-18-3,15731-88-1)

Guidance literature:

With sodium hydroxide; In not given; pptn. with NaOH, washing the ppt., treating with organic acid;

DOI:10.1023/A:1025066131365

Reference yield:

cobalt(II) nitrate → cobalt(II) formate (544-18-3,15731-88-1)

Guidance literature:

With ammonium carbonate; In formic acid; byproducts: nitrate; exchange of nitrate by carbonate; treatment with formic acid;; containing 3 molecule of water;;

upstream raw materials:

formic acid

cobalt(II) acetate

cobalt(II) carbonate

cobalt(II) formate dihydrate

Downstream raw materials:

cobaltocene

cobalt

cobalt(II) oxide

Refernces

• 1、 Rajarao, Ravindra,Bhat, Badekai Ramachandra. "Green approach to synthesize multi-walled carbon nanotubes by using metal formate as catalyst precursors". . p. 2153 - 2158. Retrieved 2013/05/22.
• 2、 Vlase,Vlase,Chiriac,Doca. "Decomposition of organic salts of some d and f metals: Non-isothermal kinetics and FT-IR studies". . p. 839 - 845. Retrieved 2008/10/08.