1-(4-Methoxyphenyl)cycloheptene

Base Information

Chemical Name:1-(4-Methoxyphenyl)cycloheptene
CAS No.:32960-45-5
Molecular Formula:C14H18O
Molecular Weight:202.296
Hs Code.:
NSC Number:127381
DSSTox Substance ID:DTXSID80298988
Nikkaji Number:J1.110.190I

Synonyms:32960-45-5;1-(4-methoxyphenyl)cycloheptene;NSC127381;DTXSID80298988;NSC-127381

Suppliers and Price of 1-(4-Methoxyphenyl)cycloheptene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 1-(4-Methoxyphenyl)cycloheptene

Chemical Property:

Vapor Pressure:0.00137mmHg at 25°C
Boiling Point:306.7°Cat760mmHg
Flash Point:119.7°C
Density:0.993g/cm³
XLogP3:5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:202.135765193
Heavy Atom Count:15
Complexity:211

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=CC=C(C=C1)C2=CCCCCC2

Technology Process of 1-(4-Methoxyphenyl)cycloheptene

There total 13 articles about 1-(4-Methoxyphenyl)cycloheptene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 628-92-2,45509-99-7
Cycloheptene

: 66107-29-7
4-methoxyphenyl triflate

: 32960-45-5
1-(4-methoxyphenyl)cyclohept-1-ene

Guidance literature:: With 1,2-dimethoxybenzene; bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)palladium(II); 1,3-bis-(diphenylphosphino)propane; lithium carbonate; at 120 ℃; for 48h; Inert atmosphere;
DOI:10.1002/chem.201204427

Reference yield: 73.0%

: 104-92-7
1-bromo-4-methoxy-benzene

: 502-42-1
cycloheptanone

: 32960-45-5
1-(4-methoxyphenyl)cyclohept-1-ene

Guidance literature:: 1-bromo-4-methoxy-benzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; Inert atmosphere;

With cerium(III) chloride; In tetrahydrofuran; hexane; at -78 ℃; for 1.5h; Inert atmosphere;

cycloheptanone; Further stages;
DOI:10.1055/s-0029-1217964

Reference yield: 54.0%

: 104-92-7
1-bromo-4-methoxy-benzene

: 2-(4-tolylsulfinyl)cyclohept-1-en-1-yl triflate

: 32960-45-5
1-(4-methoxyphenyl)cyclohept-1-ene

: 1-(1-cycloheptenyl)-2-(p-methoxyphenyl)cycloheptene

Guidance literature:: 1-bromo-4-methoxy-benzene; With magnesium; In tetrahydrofuran; Inert atmosphere;

2-(4-tolylsulfinyl)cyclohept-1-en-1-yl triflate; In tetrahydrofuran; diethyl ether; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1039/d0cc02788j