(+)-(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine

Base Information

Chemical Name:(+)-(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
CAS No.:55650-59-4
Molecular Formula:C₃₈H₃₇FeNP₂
Molecular Weight:625.513
Hs Code.:29319090
European Community (EC) Number:637-250-0
Mol file:55650-59-4.mol

Synonyms:(2S)-1-[(1S)-1-(Dimethylamino)ethyl]-1',2-bis(diphenylphosphino)ferrocene;VUJPTJYMSBMZOZ-RMRYJAPISA-N;(+)-(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine;(+)-(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine, 95%

Suppliers and Price of (+)-(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(S)-N,N-Dimethyl-1-[(R)-1'',2-bis(diphenylphosphino)ferrocenyl)ethylamine
2mg
$ 60.00

TRC
(S)-N,N-Dimethyl-1-[(R)-1'',2-bis(diphenylphosphino)ferrocenyl)ethylamine
10mg
$ 75.00

TCI Chemical
(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine >95.0%(GC)
100mg
$ 76.00

Sigma-Aldrich
(+)-(S)-N,N-Dimethyl-1-[(R)-1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine 95%
100mg
$ 80.60

Chem-Impex
(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine,≥98%(Chiralpurity) ≥98%(Chiralpurity)
100MG
$ 86.20

Biosynth Carbosynth
(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
250 mg
$ 138.00

Biosynth Carbosynth
(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
100 mg
$ 69.00

Biosynth Carbosynth
(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
50 mg
$ 40.00

Biosynth Carbosynth
(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
1 g
$ 400.00

Biosynth Carbosynth
(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
500 mg
$ 235.00

Total 20 raw suppliers

Chemical Property of (+)-(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine

Chemical Property:

Melting Point:138-142 °C(lit.)
PSA：30.42000
LogP:6.70920
Storage Temp.:under inert gas (nitrogen or Argon) at 2–8 °C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:8
Exact Mass:625.175060
Heavy Atom Count:42
Complexity:695

Purity/Quality:

95% ^*data from raw suppliers

(S)-N,N-Dimethyl-1-[(R)-1'',2-bis(diphenylphosphino)ferrocenyl)ethylamine ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xn
Hazard Codes:Xn
Statements: 20/21/22-36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC([C]1C=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3)N(C)C.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=C[CH]3.[Fe]
Isomeric SMILES:C[C@@H]([C]1C=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3)N(C)C.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=C[CH]3.[Fe]
Uses Ligand used in the asymmetric hydrogenation of (Z)-α-amido-cinnamic acids

Technology Process of (+)-(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine

There total 1 articles about (+)-(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 31904-34-4,31886-58-5,31886-57-4
N,N-dimethyl-1-ferrocenylethylamine

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 263026-96-6,69257-18-7,55650-59-4,74311-56-1,119477-32-6,131831-00-0
N,N-dimethyl-(1',2-bis(diphenylphosphino)ferrocenyl)-1-(methyl-1-methylamine)

Guidance literature:: N,N-dimethyl-1-ferrocenylethylamine; With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In diethyl ether;

chloro-diphenylphosphine;

Reference yield: 70.0%

: 12107-56-1
dichloro(cycloocta-1,5-diene)palladium (II)

: 263026-96-6,69257-18-7,55650-59-4,74311-56-1,119477-32-6,131831-00-0
N,N-dimethyl-(1',2-bis(diphenylphosphino)ferrocenyl)-1-(methyl-1-methylamine)

: 2923-28-6
silver trifluoromethanesulfonate

: 374082-41-4
[Pd(N,N'-dimethyl-1-[1',2-bis(diphenylphosphino)ferrocenyl]ethylamine)(CF₃SO₃)](CF₃SO₃)

Guidance literature:: In dichloromethane; Schlenk technique; CH2Cl2 soln. of the amine added to Pd complex in CH2Cl2, volatiles removed, residue redissolved in CH2Cl2, soln. of AgCF3SO3 in MeCN added, stirred at room temp. for 1 h; soln. filtered, volume of filtrate was reduced, Et2O was added, ppt. wasrecrystd. from CH2Cl2/pentane, dried in vac.; elem. anal.;
DOI:10.1021/om010524n