(+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE

Base Information

• Chemical Name: (+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE
• CAS No.: 31904-34-4
• Molecular Formula: C₁₄H₁₉FeN
• Molecular Weight: 257.159
• Mol file: 31904-34-4.mol

Synonyms:N,N-Dimethyl-a-ferrocenylethylamine;N,N-Dimethyl-1-ferrocenylethylamine;(1-Ferrocenylethyl)dimethylamine;Ferrocenemethylamine,N,N,a-trimethyl-, (?à)- (8CI);1-(1-cyclopenta-2,4-dienyl)-N,N-dimethyl-ethanamine; cyclopentane; iron;Ferrocene, [1-(dimethylamino)ethyl]-;

Chemical Property of (+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE

Chemical Property:

• Refractive Index: n20/D 1.587
• Boiling Point: 169.5 °C at 760 mmHg
• Flash Point: 48.8 °C
• PSA: 3.24000
• Density: 1,222 g/cm3
• LogP: 2.36080
• Water Solubility.: Not miscible or difficult to mix in water.

Purity/Quality:

99%, ^*data from raw suppliers

α-(N,N-Dimethylamino)ethylferrocene, 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/38:Irritating to eyes and skin.
• Hazard Codes: Xn
• Statements: 36/38-22
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE

There total 20 articles about (+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + (R)-α-ferrocenylethylamine → N,N-dimethyl-1-ferrocenylethylamine (31904-34-4,31886-58-5,31886-57-4)

Guidance literature:

With sodium cyanoborohydride; In methanol; for 3h; Reagent/catalyst; Reflux;

Reference yield: 95.0%

fc-CHCl(CH3) + dimethyl amine (124-40-3) → N,N-dimethyl-1-ferrocenylethylamine (31904-34-4,31886-58-5,31886-57-4)

Guidance literature:

In diethyl ether;

DOI:10.1021/ja00721a017

Reference yield: 95.0%

S-(1-ferrocenylethyl)thioglycolic acid + dimethyl amine (124-40-3) → N,N-dimethyl-1-ferrocenylethylamine (31904-34-4,31886-58-5,31886-57-4)

Guidance literature:

With ammonium chloride; mercury dichloride; In water; acetone;

upstream raw materials:

dimethyl amine

sodium tetrahydroborate

1-ferrocenylethylamine

1-ferrocenylethanol

Downstream raw materials:

vinyl ferrocene

1-(2-bis(3,5-xylyl)phosphinoferrocenyl)ethylbis(3,5-xylyl)phosphine

rac-(1-(dimesitylphosphino)ethyl)ferrocene

N,N-dimethyl-(1',2-bis(diphenylphosphino)ferrocenyl)-1-(methyl-1-methylamine)

Refernces

• 1、 -. "Synthetic method of Ugi's amines and derivatives of Ugi's amines". Paragraph 0083-0092. . Retrieved 2019/05/16.
• 2、 -. "Process for preparing (S)-1-ferrocene ethyl dimethylamine". Paragraph 0050; 0053. . Retrieved 2018/09/11.