4',4''-dibromo-4-tert-butyl-triphenyl-amine

Base Information

• Chemical Name: 4',4''-dibromo-4-tert-butyl-triphenyl-amine
• CAS No.: 852534-22-6
• Molecular Formula: C22H21Br2N
• Molecular Weight: 459.223
• Mol file: 852534-22-6.mol

Synonyms:t-butyl-N,N-bis(4-bromophenyl)aniline;t-butyl-N,N-bis-(4-bromophenyl)aniline;

Chemical Property of 4',4''-dibromo-4-tert-butyl-triphenyl-amine

Chemical Property:

• PSA: 3.24000
• LogP: 7.97890

Purity/Quality:

99% ^*data from raw suppliers

4-Bromo-N-(4-bromophenyl)-N-(4-(tert-butyl)phenyl)aniline ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: 4-Bromo-N-(4-bromophenyl)-N-(4-(tert-butyl)phenyl)aniline is a useful research reagent for organic synthesis and other chemical processes.

Technology Process of 4',4''-dibromo-4-tert-butyl-triphenyl-amine

There total 3 articles about 4',4''-dibromo-4-tert-butyl-triphenyl-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,4-bromoiodobenzene (589-87-7) + 4-tert-Butylaniline (769-92-6) → bis-(4-bromophenyl)-(4-tert-butylphenyl)amine (852534-22-6)

Guidance literature:

With 1,1'-bis-(diphenylphosphino)ferrocene; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium t-butanolate; In toluene; Reflux;

DOI:10.1021/acs.inorgchem.1c03578

Reference yield:

1-tert-butyl-4-iodobenzene (35779-04-5) → bis-(4-bromophenyl)-(4-tert-butylphenyl)amine (852534-22-6)

Guidance literature:

Multi-step reaction with 2 steps

1: diphenylamine; palladium

2: N-Bromosuccinimide

With N-Bromosuccinimide; palladium; diphenylamine;

DOI:10.1021/acs.organomet.0c00779

Reference yield:

N,N-diphenyl-N-(4-tert-butylphenyl)amine (36809-23-1) → bis-(4-bromophenyl)-(4-tert-butylphenyl)amine (852534-22-6)

Guidance literature:

With N-Bromosuccinimide;

DOI:10.1021/acs.organomet.0c00779

upstream raw materials:

1-tert-butyl-4-iodobenzene

N,N-diphenyl-N-(4-tert-butylphenyl)amine

1,4-bromoiodobenzene

4-tert-Butylaniline

Downstream raw materials:

t-butyl-N,N-bis(4-(trimethylstannyl)phenyl)aniline

4-(t-butyl)-N-(4-(trimethylsilyl)phenyl)-N-(4-(dibromoboryl)phenyl)aniline

C₆₅H₈₃BN₂Si₂

4-bromo-N-(4-(t-butyl)phenyl)-N-(4-(trimethylsilyl)phenyl)aniline

Refernces

• 1、 Baser-Kirazli, Nurcan,Lalancette, Roger A.,J?kle, Frieder. "Tuning the Donor-π-Acceptor Character of Arylborane-Arylamine Macrocycles". . p. 520 - 528. Retrieved 2021/02/27.