36809-23-1

Basic information

• Product Name: Benzenamine, 4-(1,1-dimethylethyl)-N,N-diphenyl-
• CAS NO: 36809-23-1
• Molecular Formula: C22H23N
• Molecular Weight: 301.431
• Mol File: 36809-23-1.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-(1,1-dimethylethyl)-N,N-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-(1,1-dimethylethyl)-N,N-diphenyl-(36809-23-1)
• EPA Substance Registry System: Benzenamine, 4-(1,1-dimethylethyl)-N,N-diphenyl-(36809-23-1)

Safety Data

• Hazardous Substances Data: 36809-23-1(Hazardous Substances Data)

Upstream product

• 1943-67-5 4-(t-butyl)phenyl isocyanate 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 98-54-4 para-tert-butylphenol 
• 59970-38-6 4-tert-butylphenyl mesylate 
• 122-39-4 diphenylamine 
• 62-53-3 aniline 
• 160788-98-7 4-(tert-butyl)phenyl benzenesulfonate 
• 3972-65-4 1-bromo-4-tert-butylbenzene 
• 3972-56-3 4-(tert-butyl)chlorobenzene 
• 640-60-8 toluene-4-sulfonic acid phenyl ester 
• 35779-04-5 1-tert-butyl-4-iodobenzene 

Downstream Products

• 852534-22-6 bis-(4-bromophenyl)-(4-tert-butylphenyl)amine 
• 1370333-01-9 (E)-3-(4-(5-(4-(N-(4-tert-butylphenyl)-N-phenyl)aminophenyl)thiophen-2-yl)phenyl)-2-cyanoacrylic acid 
• 1370333-09-7 4-(5-(4-((4-tert-butylphenyl)phenylamino)phenyl)thiophen-2-yl)benzaldehyde 
• 1384096-18-7 N-(4-tert-butylphenyl)-N-phenyl-4-(thiophen-2-yl)benzenamine 
• 1298077-62-9 4-tert-butyl-N-(4-bromophenyl)-N-phenylbenzenamine 

Relevant articles and documents

Synthesis of two novel dinuclear palladium(I) complexes and studies of their catalytic activity in amination reactions

Two novel palladium(I) dinuclear complexes have been prepared and their structural characterization has revealed an unprecedented μ2- η3:η3 coordination between a phenyl ring from PtBu2Bph (Bph = Biphenyl) and the PdI-Pd I unit present in the complexes.

DIARYL AMINE COMPOUND AND METHOD FOR PRODUCING THE SAME

The present invention relates to a process for the preparation of diaryl amine compounds. A compound represented by chemical formula 1, a compound represented by chemical formula 2, and a synthetic reagent in a solvent, the synthetic reagent being CsF, KF, 18 - crown -6, K. 2 CO3, [TBAT] The present invention relates to a process for the preparation of diaryl amine compounds comprising a material selected from the group consisting of a (tetrabutylammonium difluorotriphenylsilicate), TBAF (tetrabutylammonium fluoride) and combinations thereof. Chemical Formula 1. Chemical Formula 2. The diaryl amine compound can be synthesized under the absence of a transition metal to be used to synthesize diaryl amine compounds having various substituents.

(DiMeIHeptCl)Pd: A Low-Load Catalyst for Solvent-Free (Melt) Amination

(DiMeIHeptCl)Pd, a hyper-branched N-aryl Pd NHC catalyst, has been shown to be efficient at performing amine arylation reactions in solvent-free ("melt") conditions. The highly lipophilic environment of the alkyl chains flanking the Pd center serves as lubricant to allow the complex to navigate through the paste-like environment of these mixtures. The protocol can be used on a multi-gram scale to make a variety of aniline derivatives, including substrates containing alcohol moieties.

Transition-Metal-Free Diarylation of Isocyanates with Arynes

A facile method for the transition-metal-free diarylation of isocyanates with arynes in the presence of cesium fluoride has been developed, which affords functionalized diaryl amines in moderate to excellent yields. This reaction has good functional group tolerance and provides excellent regioselectivity by utilizing a methoxy-substituted aryne precursor.