1-BroMobutane-1d4

Base Information

• Chemical Name: 1-BroMobutane-1d4
• CAS No.: 1219805-80-7
• Molecular Formula: CH3CH2CD2CD2Br
• Molecular Weight: 141.04
• Mol file: 1219805-80-7.mol

Synonyms:

Chemical Property of 1-BroMobutane-1d4

Chemical Property:

Purity/Quality:

98% ^*data from raw suppliers

1-Bromobutane-1,1,2,2-d4 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-BroMobutane-1d4

There total 2 articles about 1-BroMobutane-1d4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

butan-1,1,2,2,3,3,4,4,4-d9-1-ol-d (34193-38-9,118104-91-9,64118-16-7) → n-butyl-2H9 bromide (98195-36-9,1219805-80-7)

Guidance literature:

With sulfuric acid; hydrogen bromide; for 3h; Reflux;

DOI:10.3390/molecules26195828

Reference yield: 56.4%

<1,1,2,2,3,3,4,4,4-D9>Butanol (25493-17-8,118104-91-9,64118-16-7) → n-butyl-2H9 bromide (98195-36-9,1219805-80-7)

Guidance literature:

With sulfuric acid; hydrogen bromide; for 3h; Inert atmosphere; Reflux;

DOI:10.1002/jlcr.3498

Reference yield: 70.0%

n-butyl-2H9 bromide (98195-36-9,1219805-80-7) + tin(IV) chloride (7646-78-8) → tetra(n-butyl-d9)stannane (358731-92-7)

Guidance literature:

n-butyl-²H₉ bromide; With magnesium; In diethyl ether; at 20 ℃; Inert atmosphere; Schlenk technique;

tin(IV) chloride; In benzene; at 0 - 20 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1021/jacs.5b07672

upstream raw materials:

butan-1,1,2,2,3,3,4,4,4-d9-1-ol-d

<1,1,2,2,3,3,4,4,4-D9>Butanol

Downstream raw materials:

n-butane-d9

d9-pentanenitrile

tetra(n-butyl-d9)stannane

Refernces

• 1、 Ivanov, Mikhail Yu.,Prikhod’ko, Sergey A.,Bakulina, Olga D.,Kiryutin, Alexey S.,Adonin, Nicolay Yu.,Fedin, Matvey V.. "Validation of structural grounds for anomalous molecular mobility in ionic liquid glasses". . . Retrieved 2021/10/01.