N-(4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl)aniline

Base Information

Chemical Name:N-(4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl)aniline
CAS No.:1029439-56-2
Molecular Formula:C19H24BNO2
Molecular Weight:309.216
Hs Code.:2931900090
European Community (EC) Number:806-667-1
DSSTox Substance ID:DTXSID10590407
Wikidata:Q82484107
Mol file:1029439-56-2.mol

Synonyms:1029439-56-2;N-(4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl)aniline;4-(N-PHENYLAMINOMETHYL)PHENYLBORONIC ACID, PINACOL ESTER;N-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methyl}aniline;N-[[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methyl]aniline;[4-(Phenylaminomethyl)phenyl]-boronic acid pinacol ester;4-(N-Phenylaminomethyl)phenylboronic acid pinacol ester;4-(N-Phenylaminomethyl)phenylboronic acid, pinacol ester, AldrichCPR;SCHEMBL10269020;DTXSID10590407;4-(PHENYLAMINOMETHYL)BENZENEBORONIC ACID PINACOL ESTER;4-(PHENYLAMINOMETHYL)PHENYLBORONIC ACID PINACOL ESTER;MFCD06795652;AKOS015960127;AB29172;AS-2296;DA-48265;CS-0174661;E84007;4-(N-PHENYLAMINOMETHYL)PHENYLBORONIC ACID;A907075;J-000846

Suppliers and Price of N-(4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl)aniline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-(N-Phenylaminomethyl)phenylboronic acid, pinacol ester
100mg
$ 60.00

Sigma-Aldrich
4-(N-Phenylaminomethyl)phenylboronic acid, pinacol ester Aldrich
1g
$ 144.00

Matrix Scientific
[4-(Phenylaminomethyl)phenyl]-boronic acid pinacol ester >95%
5g
$ 498.00

Matrix Scientific
[4-(Phenylaminomethyl)phenyl]-boronic acid pinacol ester >95%
500mg
$ 113.00

Matrix Scientific
[4-(Phenylaminomethyl)phenyl]-boronic acid pinacol ester >95%
1g
$ 152.00

Crysdot
N-(4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl)aniline 95+%
10g
$ 368.00

Apolloscientific
[4-(Phenylaminomethyl)phenyl]-boronicacidpinacolester
1g
$ 131.00

Apolloscientific
[4-(Phenylaminomethyl)phenyl]-boronicacidpinacolester
500mg
$ 109.00

Apolloscientific
[4-(Phenylaminomethyl)phenyl]-boronicacidpinacolester
5g
$ 340.00

American Custom Chemicals Corporation
4-(N-PHENYLAMINOMETHYL)PHENYLBORONIC ACID, PINACOL ESTER 95.00%
5G
$ 1129.08

Total 13 raw suppliers

Chemical Property of N-(4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl)aniline

Chemical Property:

Boiling Point:440.4±28.0 °C(Predicted)
PKA:3.76±0.10(Predicted)
PSA：30.49000
Density:1.07±0.1 g/cm3(Predicted)
LogP:3.67090
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:309.1900092
Heavy Atom Count:23
Complexity:369

Purity/Quality:

97% ^*data from raw suppliers

4-(N-Phenylaminomethyl)phenylboronic acid, pinacol ester ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36
Safety Statements: 26

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C2=CC=C(C=C2)CNC3=CC=CC=C3

Technology Process of N-(4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl)aniline

There total 6 articles about N-(4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl)aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 62-53-3
aniline

: 128376-64-7
4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde

: 1029439-56-2
N-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl)aniline

Guidance literature:: With (2,6-dichlorophenyl)bis(2,3,5,6-tetrafluorophenyl)borane; hydrogen; In tetrahydrofuran; at 100 ℃; for 6h; under 15201 Torr; Sealed tube; Molecular sieve; Autoclave; Green chemistry;
DOI:10.1021/jacs.8b03626

Reference yield: 65.0%

: 62-53-3
aniline

: 138500-85-3
4-bromomethylphenylboronic acid pinacol ester

: 1029439-56-2
N-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl)aniline

Guidance literature:: With caesium carbonate; In N,N-dimethyl-formamide; for 18h;

Reference yield: 52.0%

: 62-53-3
aniline

: 302348-51-2
(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)methanol

: 1029439-56-2
N-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl)aniline

Guidance literature:: With [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; sodium carbonate; bis[2-(diphenylphosphino)phenyl] ether; In 5,5-dimethyl-1,3-cyclohexadiene; at 155 ℃; for 24h; Inert atmosphere; Reflux;
DOI:10.1021/ol402271a