R-3,3'-Bis(3,5-bis(methyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

Base Information

Chemical Name:R-3,3'-Bis(3,5-bis(methyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
CAS No.:861909-53-7
Molecular Formula:C₃₆H₂₉O₄P
Molecular Weight:556.598
Hs Code.:2809200000
Mol file:861909-53-7.mol

Synonyms:(R)-3,3'-Bis(3,5-bismethyl-phenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate;

Suppliers and Price of R-3,3'-Bis(3,5-bis(methyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

SynQuest Laboratories
(R)-3,3'-Bis[3,5-dimethylphenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate
250 mg
$ 776.00

Strem Chemicals
(11bR)-2,6-Bis(3,5-dimethylphenyl)-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)
100mg
$ 245.00

Matrix Scientific
(R)-3,3'-Bis[3,5-dimethylphenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 98.1%
250mg
$ 638.00

Matrix Scientific
(R)-3,3'-Bis[3,5-dimethylphenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 98.1%
500mg
$ 1088.00

Matrix Scientific
(R)-3,3'-Bis[3,5-dimethylphenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 98.1%
1g
$ 1726.00

Crysdot
(11bR)-2,6-Bis(3,5-dimethylphenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%
1g
$ 1713.00

Ambeed
(11bR)-2,6-Bis(3,5-dimethylphenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 97%
100mg
$ 65.00

Ambeed
(11bR)-2,6-Bis(3,5-dimethylphenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 97%
1g
$ 455.00

Ambeed
(11bR)-2,6-Bis(3,5-dimethylphenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 97%
250mg
$ 135.00

Aaron Chemicals
(11bR)-2，6-Bis(3，5-dimethylphenyl)-4-hydroxy-4-oxide-dinaphtho[2，1-d:1'，2'-f][1，3，2]dioxaphosphepin 97%
250mg
$ 121.00

Total 11 raw suppliers

Chemical Property of R-3,3'-Bis(3,5-bis(methyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

Chemical Property:

Boiling Point:755.9±70.0 °C(Predicted)
PKA:1.11±0.20(Predicted)
PSA：65.57000
Density:1.35±0.1 g/cm3(Predicted)
LogP:10.09920

Purity/Quality:

99% ^*data from raw suppliers

(R)-3,3'-Bis[3,5-dimethylphenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of R-3,3'-Bis(3,5-bis(methyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

There total 4 articles about R-3,3'-Bis(3,5-bis(methyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 215433-51-5
(S)-3,3’-bis(3,5-dimethylphenyl)-[1,1‘-binaphthalene]-2,2’-diol

: 1170736-59-0,861909-53-7
C₃₆H₂₉O₄P

Guidance literature:: (S)-3,3’-bis(3,5-dimethylphenyl)-[1,1‘-binaphthalene]-2,2’-diol; With pyridine; trichlorophosphate; for 5h; Inert atmosphere;

With water; In pyridine; for 0.5h;
DOI:10.1021/ol901114f

Reference yield:

: 75640-87-8
(S)-2,2'-dimethoxy-1,1'-dinaphthyl

: 1170736-59-0,861909-53-7
C₃₆H₂₉O₄P

Guidance literature:: Multi-step reaction with 4 steps

1.1: bromine / dichloromethane / 1 h / 0 °C

2.1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tricyclohexylphosphine; potassium fluoride / tetrahydrofuran / 18 h / Reflux

3.1: boron tribromide / dichloromethane / 1 h / 0 °C

4.1: trichlorophosphate / pyridine / 5 h / Inert atmosphere

4.2: 0.5 h / Inert atmosphere

With potassium fluoride; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; bromine; boron tribromide; trichlorophosphate; tricyclohexylphosphine; In tetrahydrofuran; pyridine; dichloromethane; 2.1: |Suzuki Coupling / 3.1: |Suzuki Coupling;
DOI:10.1021/ol5028255

Reference yield:

: 75714-60-2
(S)-3-bromo-1-(3-bromo-2-methoxynaphthalen-1-yl)-2-methoxynaphthalene

: 1170736-59-0,861909-53-7
C₃₆H₂₉O₄P

Guidance literature:: Multi-step reaction with 3 steps

1.1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tricyclohexylphosphine; potassium fluoride / tetrahydrofuran / 18 h / Reflux

2.1: boron tribromide / dichloromethane / 1 h / 0 °C

3.1: trichlorophosphate / pyridine / 5 h / Inert atmosphere

3.2: 0.5 h / Inert atmosphere

With potassium fluoride; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; boron tribromide; trichlorophosphate; tricyclohexylphosphine; In tetrahydrofuran; pyridine; dichloromethane; 1.1: |Suzuki Coupling / 2.1: |Suzuki Coupling;
DOI:10.1021/ol5028255