Tributylstannanylium;trifluoromethanesulfonate

Base Information

Chemical Name:Tributylstannanylium;trifluoromethanesulfonate
CAS No.:68725-14-4
Molecular Formula:C13H27F3O3SSn
Molecular Weight:439.127
Hs Code.:29312000
DSSTox Substance ID:DTXSID40475197
Mol file:68725-14-4.mol

Synonyms:tributylstannanylium;trifluoromethanesulfonate;SCHEMBL9365930;DTXSID40475197;AKOS027470123;tri-n-Butyl(trifluoromethane-sulfonate)tin;FT-0721100

Suppliers and Price of Tributylstannanylium;trifluoromethanesulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Tri-n-butyltin trifluoromethanesulfonate
100mg
$ 60.00

Sigma-Aldrich
Tributylstannyl trifluoromethanesulfonate 90%
1g
$ 48.00

Matrix Scientific
Tributylstannyl trifluoromethanesulfonate
5g
$ 339.00

Alfa Aesar
Tri-n-butyltin trifluoromethanesulfonate tech. 90%
5g
$ 142.00

Alfa Aesar
Tri-n-butyltin trifluoromethanesulfonate tech. 90%
1g
$ 37.70

Alfa Aesar
Tri-n-butyltin trifluoromethanesulfonate tech. 90%
250mg
$ 12.60

Total 23 raw suppliers

Chemical Property of Tributylstannanylium;trifluoromethanesulfonate

Chemical Property:

Vapor Pressure:0.000161mmHg at 25°C
Melting Point:31 °C
Boiling Point:56 °C
Flash Point:>230 °F
PSA：51.75000
LogP:6.27920
Storage Temp.:2-8°C
Sensitive.:Moisture Sensitive
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:9
Exact Mass:440.065503
Heavy Atom Count:21
Complexity:217

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tri-n-butyltin trifluoromethanesulfonate ^*data from reagent suppliers

Safty Information:

Pictogram(s): T,N
Hazard Codes:T,N
Statements: 21-25-36/38-48/23/25-50/53
Safety Statements: 35-36/37/39-45-60-61

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC[Sn+](CCCC)CCCC.C(F)(F)(F)S(=O)(=O)[O-]

Technology Process of Tributylstannanylium;trifluoromethanesulfonate

There total 2 articles about Tributylstannanylium;trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 88016-29-9
μ-oxobis[(trifluoromethanesulfonato)(phenyl)iodine]

: 144241-73-6
4,4-dimethyl-1-(tributylstannyl)-2-pentyne

: 26981-77-1
t-butylallene

: 131251-47-3
4,4-dimethyl-1-(2-iodophenyl)-2-pentyne

: 68725-14-4
tributylstannyl trifluoromethanesulfonate

Guidance literature:: In chloroform; at -30 ℃;
DOI:10.1021/jo00050a024

Reference yield:

: 688-73-3
tri-n-butyl-tin hydride

: 142581-66-6
(N(CH₃)2)C₆H₄CHC₆H₄(N(CH₃)2)⁽¹⁺⁾*CF₃SO₃^(1-) = CF₃SO₃{(N(CH₃)2)C₆H₄CHC₆H₄(N(CH₃)2)}

: 101-61-1
4,4'-methylene-bis(N,N-dimethylaniline)

: 68725-14-4
tributylstannyl trifluoromethanesulfonate

Guidance literature:: In dichloromethane; at -70 ℃; Kinetics; Rate constant; ΔH(excit), ΔS(excit);

Reference yield: 92.0%

: 68725-14-4
tributylstannyl trifluoromethanesulfonate

: 41593-58-2
diphenylphosphineborane

: 1252594-30-1
(C₆H₅)2P(BH₃)((C₄H₉)3Sn)

Guidance literature:: With 2,2,6,6-tetramethylpiperidine; In dichloromethane; byproducts: H2; N2 or Ar; MeCN soln. of nBu3nOTf (0.55 mmol) and 2,2,6,6-tetramethylpiperidine (0.55 mmol) added to soln. of B compd. (0.5 mmol), mixt. stirredat 20°c for 4 h; ppt. filtered off, evapd.;
DOI:10.1002/ejic.201000515