Tributyl(4,5-dihydrofuran-2-yl)stannane

Base Information

Chemical Name:Tributyl(4,5-dihydrofuran-2-yl)stannane
CAS No.:125769-77-9
Molecular Formula:C16H32OSn
Molecular Weight:359.139
Hs Code.:
European Community (EC) Number:682-759-3
DSSTox Substance ID:DTXSID20558912
Mol file:125769-77-9.mol

Synonyms:125769-77-9;Tributyl(4,5-dihydrofuran-2-yl)stannane;tributyl(2,3-dihydrofuran-5-yl)stannane;Tributyl(4,5-dihydro-2-furyl)stannane;Tributyl(4,5-dihydrofuran-2-yl)tin;SCHEMBL2390664;DTXSID20558912;QTYBKWIPVOTUQI-UHFFFAOYSA-N;MFCD18785742;5-(tributylstannyl)-2,3-dihydrofuran;AKOS032949914;SY060871;Stannane, tributyl(4,5-dihydro-2-furanyl)-;tri-n-butyl(4,5-dihydrofuran-2-yl)stannane;tributyl-(4,5-dihydro-furan-2-yl)-stannane;EN300-267123;H11418;Tributyl(4,5-dihydrofuran-2-yl)stannane, 97%;A920156

Suppliers and Price of Tributyl(4,5-dihydrofuran-2-yl)stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Tributyl(4,5-dihydrofuran-2-yl)stannane
250mg
$ 90.00

TRC
Tributyl(4,5-dihydrofuran-2-yl)stannane
25mg
$ 45.00

Sigma-Aldrich
Tributyl(4,5-dihydrofuran-2-yl)stannane 97%
5g
$ 246.00

Sigma-Aldrich
Tributyl(4,5-dihydrofuran-2-yl)stannane 97%
1g
$ 74.20

Total 32 raw suppliers

Chemical Property of Tributyl(4,5-dihydrofuran-2-yl)stannane

Chemical Property:

Refractive Index:n20/D 1.493
Boiling Point:361.4±52.0 °C(Predicted)
Flash Point:>110°C
PSA：9.23000
Density:1.128g/mLat 25℃
LogP:4.66920
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:10
Exact Mass:360.147518
Heavy Atom Count:18
Complexity:226

Purity/Quality:

97% ^*data from raw suppliers

Tributyl(4,5-dihydrofuran-2-yl)stannane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:T,N
Statements: 21-25-36/38-48/23/25-50/53
Safety Statements: 35-36/37/39-45-60-61

MSDS Files:: Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)C1=CCCO1
Uses Tributyl(4,5-dihydrofuran-2-yl)stannane is an organotin compound (or organostannane), which can be used as a reactant: In the palladium-catalyzed Stille coupling reaction to prepare furan-containing aryl derivatives by reacting with various aryl halides. To synthesize 2,3-dihydro-5-(2-methylphenyl)furan by coupling with 2-iodotoluene in the presence of a palladium catalyst. In the chemoselective preparation of hexatrienes by the tandem palladium-catalyzed Heck and Stille coupling of bromohexenyl triflates and acrylates.

Technology Process of Tributyl(4,5-dihydrofuran-2-yl)stannane

There total 4 articles about Tributyl(4,5-dihydrofuran-2-yl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1191-99-7,75454-45-4
2,3-dihydro-2H-furan

: 1461-22-9
tributyltin chloride

: 125769-77-9
tributyl-(4,5-dihydro-furan-2-yl)-stannane

Guidance literature:: 2,3-dihydro-2H-furan; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -60 - 0 ℃; for 1h;

tributyltin chloride; In tetrahydrofuran; pentane; at -60 - 0 ℃; for 1.5h;

With water; ammonium chloride; In tetrahydrofuran; pentane;

Reference yield: 99.0%

: 1191-99-7,75454-45-4
2,3-dihydro-2H-furan

: 7440-31-5
stannane

: 149732-36-5
4-iodobenzo[b]thiophene-2-carboxamidine hydrochloride

: 1461-22-9
tributyltin chloride

: 146137-85-1
methyl 4-iodobenzo[b]thiophene-2-carboxylate

: 125769-77-9
tributyl-(4,5-dihydro-furan-2-yl)-stannane

Guidance literature:: With tert.-butyl lithium; lithium chloride; bis(triphenylphosphine)palladium(II)-chloride; In N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide;

Reference yield: 64.0%

: 68725-14-4
tributylstannyl trifluoromethanesulfonate

: 927-74-2
3-Butyn-1-ol

: 125769-77-9
tributyl-(4,5-dihydro-furan-2-yl)-stannane

Guidance literature:: With hexacarbonyl molybdenum; triethylamine; In diethyl ether; Irradiation (UV/VIS); N2-atmosphere; irradn. (20 min), alkynyl alcohol and Sn-compd. addn., stirring (18 h); evapn., chromy. (SiO2, pentane / Et2O / 1% Et2NH);